Eight kinds of heavy metals in soil within 0–2 km from the banks of Shuimo River in Urumqi were analyzed by using an X-ray fluorescence spectrometer and national standard detection methods. Unmix and PMF models are comprehensively used to analyze potential pollutant sources and contribution rates. Soil samples are sampled in three layers of 0–20, 20–40, and 40–60 cm, and each group of sample points in each layer is 5 m, 1 km, and 2 km away from the riverbank, respectively. Only the average concentration of Mn in each layer of soil is lower than the background value, according to the analytical results, while the average concentration of other heavy metals surpasses the background value. The highest proportion of exceeding the background value is Ni in the 40–60 cm soil layer, up to 1.92 times. Unmix and PMF models are used to analyze pollutants’ source quantity and contribution rate, respectively. The results show that the two models can identify two pollution sources at the three soil layers, and their contribution rates are similar, and each index of the analysis results of the two models is within the required range of model reliability. By comparing with the Pearson correlation coefficient and distribution map of heavy metal concentration in surface soil, it is concluded that Zn, Pb, Cr, and Cu are mainly from industrial sewage and air pollution from coal combustion, while As, Mn, Ni, and V are mainly from agricultural pollution and light industrial pollution. In future research, it is necessary to investigate the change of heavy metal concentration in detail from the time dimension to further quantitatively calculate the potential pollutant source and contribution rate.
Soil samples were collected from the upstream, midstream and downstream areas of the Shuimo River in three layers of 0–20, 20–40 and 40–60 cm, and each group of sample points was located 5 m, 1 km and 2 km away from the river bank, respectively. The analysis was carried out. Based on the investigation and research, six indicators, including As, Pb, Zn, Cu, Ni and Cr, were designated as evaluation factors in combination with the results of the sample collection with low or no detectable values of Cd and Hg. The mean values of the samples measured in the upper, middle and downstream layers were taken, and the degree and source of pollution were evaluated and jointly analyzed using the gray correlation analysis and factor analysis methods. By using the gray correlation analysis, it was found that the evaluation results of the upstream and middle reaches of the soil along the Shuimo River were both level 3, with slight pollution, and the evaluation results of the downstream areas were level 2, with good soil quality. There are two main sources of pollution obtained through the factor analysis; source 1 is mainly heavy metals such as Zn, Cu, Cr, Pb and Ni, while source 2 is mainly heavy metals such as As, Pb and Ni. The amount of pollution sources is inferred from the heavy metal types of each source and the soil environment along the Shuimo River as industrial and human sources of pollution. From the analysis results, the combination of the gray correlation analysis model and factor analysis model is convenient and fast and can accurately quantify the source contribution of various pollution sources. Not only can it reflect the actual situation more objectively and realistically in the evaluation of soil heavy metal pollution and pollution sources, but also the calculation is simple and easily applied with low data requirements.
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