Bimetal catalysts are good alternatives for non-enzymatic glucose sensors owing to their low cost, high activity, good conductivity, and ease of fabrication. In the present study, a self-supported CuNi/C electrode prepared by electrodepositing Cu nanoparticles on a Ni-based metal–organic framework (MOF) derivate was used as a non-enzymatic glucose sensor. The porous construction and carbon scaffold inherited from the Ni-MOF guarantee good kinetics of the electrode process in electrochemical glucose detection. Furthermore, Cu nanoparticles disturb the array structure of MOF derived films and evidently enhance their electrochemical performances in glucose detection. Electrochemical measurements indicate that the CuNi/C electrode possesses a high sensitivity of 17.12 mA mM−1 cm−2, a low detection limit of 66.67 nM, and a wider linearity range from 0.20 to 2.72 mM. Additionally, the electrode exhibits good reusability, reproducibility, and stability, thereby catering to the practical use of glucose sensors. Similar values of glucose concentrations in human blood serum samples are detected with our electrode and with the method involving glucose-6-phosphate dehydrogenase; the results further demonstrate the practical feasibility of our electrode.
Electronic supplementary materialThe online version of this article (10.1007/s40820-017-0178-9) contains supplementary material, which is available to authorized users.
Organic molecules have been considered promising energy‐storage materials in aqueous zinc‐ion batteries (ZIBs), but are plagued by poor conductivity and structural instability because of the short‐range conjugated structure and low molecular weight. Herein, an imine‐based tris(aza)pentacene (TAP) with extended conjugated effects along the CN backbones is proposed, which is in situ injected into layered MXene to form a TAP/Ti3C2Tx cathode. Theoretical and electrochemical analyses reveal a selective H+/Zn2+ co‐insertion/extraction mechanism in TAP, which is ascribed to the steric effect on the availability of active CN sites. Moreover, Ti3C2Tx, as a conductive scaffold, favors fast Zn2+ diffusion to boost the electrode kinetics of TAP. Close electronic interactions between TAP and Ti3C2Tx preserve the structural integrity of TAP/Ti3C2Tx during the repeated charge/discharge. Accordingly, the TAP/Ti3C2Tx cathode delivers a high reversible capacity of 303 mAh g−1 at 0.04 A g−1 in aqueous ZIBs, which also realizes an ultralong lifetime over 10 000 cycles with a capacity retention of 81.6%. Furthermore, flexible Zn||TAP/Ti3C2Tx batteries with a quasi‐solid‐state electrolyte demonstrate potential application in wearable electronic devices. This work offers pivotal guidance to create highly stable organic electrodes for advanced ZIBs.
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