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Turbulence data from experiments conducted over a staggered cube array, modelling a neutrally stable atmospheric boundary layer in an urban environment, are presented. The results support the contention that organised eddy structures in the near-wall region differ significantly from those in regular smooth-wall flows or in rough-wall boundary layers with much smaller h/δ ratios (where δ and h are the boundary-layer thickness and the height of the roughness elements, respectively). Attention is concentrated on spatial correlations, spectra (and thus the dominant length and time scales), maps of anisotropy invariants and quadrant analyses of the stress tensor. Results are obtained within both the roughness sublayer (i.e. the region above the roughness but within which the flow is spatially inhomogeneous) and the canopy region (i.e. below the height of the roughness elements) and discussion includes consideration of the turbulence kinetic energy balance at various heights.

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Ir complex was doped to conjugated polymers, and the photoinduced absorption of triplet excitons in host materials was examined. A greatly enhanced intersystem crossing rate was observed, despite the decrease in triplet exciton lifetime. The authors find that the steady-state triplet exciton population in host polymer would increase by an order of magnitude. Conjugated polymer/colloidal CdSe nanocrystal hybrid solar cells were fabricated and the effect of Ir-complex doping on photovoltaic response was studied. It was found that due to the enhanced singlet-to-triplet conversion, greatly enhanced photovoltaic response of these hybrid organic solar cells was observed. The results suggest that triplet solar cells may be achieved by doping conventional photovoltaic materials with transition-metal complexes.