Recent progress has shown that molecular orientation in vapor-deposited glasses can affect device performance. The deposition process can result in films where the molecular axis of the glass material is preferentially ordered to lie parallel to the plane of the substrate. Here, materials made within Dow's Electronic Materials business showed enhanced performance when the orientation of the molecules, as measured by variable angle spectroscopic ellipsometry, was oriented in a more parallel fashion as compared to other materials. For one material, the anisotropic packing was observed in the as-deposited glass and was isotropic for solution-cast and annealed films. In addition, the density of an as-deposited N,N′-bis(naphthalene-1-yl)-N,N′-bis(phenyl)-2,2′-dimethylbenzidine (NPD) film was 0.8% greater than what was realized from slowly cooling the supercooled liquid. This enhanced density indicated that vapor-deposited molecules were packing more closely in addition to being anisotropic. Finally, upon heating the NPD film into the supercooled liquid state, both the density and anisotropic packing of the as-deposited glass was lost.
Metasurfaces, benefiting from the flexibility in engineering the resonance, near-field, symmetry, and scattering properties of individual building blocks, are promising not only for a wide range of practical applications in the classical linear optical regime, but also facilitate research into new unconventional areas. Very recently, we have been witnessing the second quantum revolution in which quantum information processing and computation are becoming a reality. In this review, we will focus on some of the emerging developments of metasurfaces that work in the nonlinear, non-Hermitian, nonclassical, or quantum regime. We review some of the common principles shared by the development of these metasurfaces, including local field enhancement and the consideration of structure, lattice, and time-reversal symmetries.
We propose the concept of one-sided quantum interference based on non-Hermitian metasurfaces. By designing bianisotropic metasurfaces with a non-Hermitian exceptional point, we show that quantum interference can exist only on only one side but not another. This is the quantum inheritance of unidirectional zero reflection in classical optics. The one-side interference can be further manipulated with tailor-made metasurface. With two photons simultaneously entering the metasurface from different sides, the probability for only outputting one photon on the side with reflection can be modified to zero as a one-sided destructive quantum interference while the output on another side is free of interference. We design the required bianisotropic metasurface and numerically demonstrate the proposed effect. The non-Hermitian bianisotropic metasurfaces provide more degrees of freedom in tuning two-photon quantum interference, in parallel to the celebrated Hong-Ou-Mandel effect.
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