Without the auxiliary involvement of axial ligands and organic solvents, the ionic manganese porphyrin (1c) with a pyridinium tag embedded in a pyridinium based ionic liquid, [BPy][BF 4 ], efficiently catalyzed the oxidation of styrene and its derivatives under mild conditions, affording high activity/oxide selectivity and good stability even after 5 recycling uses.
Immobilized in the Similarly Structured Ionic Liquid. -Without the auxiliary involvement of axial ligands and organic solvents an ionic manganese porphyrin, immobilized in a similarly structured ionic liquid, catalyzes the oxidation of styrene derivatives (I) under mild conditions. The system exhibits high activity and selectivity as well as good stability even after 5 recycling uses. -(LIU, Y.; ZHANG, H.-J.; CAI, Y.-Q.; WU, H.-H.; LIU, X.-L.; LU*, Y.; Chem. Lett. 36 (2007) 7, 848-849; Shanghai Key Lab. Green Chem. Chem. Process, East China Norm. Univ., Shanghai 200062, Peop. Rep. China; Eng.) -M. Paetzel 50-117
Without the auxiliary involvement of axial ligands and organic solvents, the ionic manganese porphyrin 1c immobilized in [BPy][BF4] efficiently catalyzed the oxidation of styrene and its derivatives under mild conditions, affording high activity/oxide selectivity and good stability even after 5 recycling uses.
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