Traffic-related facilities typically have much lower metal emissions than other sources; however, they can be numerous and widespread as well. Subdividing pollution sources is necessary to assess soil contamination characteristics and identify sources according to the contamination cause. Anthropogenic contamination by metals was quantitatively determined using contamination factor (Cf) and evaluated using multivariate analysis. More than half of the concentrations for Zn, Pb, and Cu in soils were higher than that in the natural background (NB). Cf of metals was, in decreasing order, Zn > Pb = Cu > Ni = As. Zn, Pb, and Cu were identified as anthropogenic contaminants in correlation analysis. Principal component analysis showed that the two main contamination causes were coarse particles from the maintenance or crushing activities of vehicles and nonexhaust/exhaust emissions. Clusters were classified according to those two anthropogenic and lithogenic causes and included Group I (Zn, Pb, and Cu in garages, auto repair shops, and auto salvage yards), Group II (Zn, Pb, and Cu in parking lots, driving schools, and roadsides), and Group III (As and Ni with high lithogenic properties). Anthropogenic input and sources of soil contamination by metals in traffic-related facilities were appropriately estimated through the combination of Cf and multivariate analysis.
This study was performed to provide fundamental data to establish the new soil pollution standards and the soil contamination management plans in a rational manner. The distribution characteristics of new soil contaminants such as barium (Ba) and chromium (Cr) in soils (n=140) were investigated in relation to land-use classification and geological features. Also, the sequential extraction test was conducted to evaluate fate and mobility of new soil contaminants. The soil samples taken from 140 sites were analyzed to survey distribution levels of selected new soil contaminants. The average concentration and range for hazardous metals (Ba, Cr) were Ba 128.946 (26.757~489.587) mg/kg, Cr 30.121 (2.579~132.783) mg/kg. Based on land use classification, the highest Ba concentration was found in factory soils, followed by dry field and park soils, while Cr concentration was highest in rice paddy soils, followed by dry field and factory soils. Within 10 geological units investigated the highest Ba and Cr concentrations were observed in the soils from Okcheon group and metamorphic rocks, respectively. The BCR (European Community Bureau of Reference) sequential extraction was conducted to identify chemical distributional existence of 2 elements of soils from each geological unit. Ba in soils is mainly assumed to exists as reducible form (such as BaSO 4 , BaCO 3 ) and Cr in soils mainly is assumed to exist as residual form (such as Cr 2 O 3, Cr x Fe 1-x (OH) 3 (x < 1)).
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