A modular and generic method for the Buchwald-Hartwig amination reactions of relatively unreactive aryl esters as acyl electrophiles and aryl chlorides as aryl electrophiles is developed, delivering efficient synthesis of...
A facile photoinduced successive oxidative ring-opening and borylation of indolizines with NHC–boranes via a one-pot method has been unveiled. This photo-promoted strategy enables the formation of unsaturated NHC–boryl carboxylates under transition metal-free conditions.
The asymmetric unit of the title compound, [PtCl2(C15H20N2S)], comprises one PtII ion, one N-heterocyclic carbene(NHC)-thioether ligand and two chloride ions. The PtII ion is four-coordinated by one C atom and one S atom of the NHC-thioether ligand, and by two chloride ions, forming an approximately square-planar geometry. In the crystal, the molecules are linked via C—H...Cl and C—H...π interactions, forming a layer parallel to the ab plane.
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