A stacked structure composed of three organic photodetectors that were individually sensitive to only one of the primary color components was fabricated based on tetra(4-methoxyphenyl) porphine cobalt complex, NN 0 -dimethylquinacridone, or zinc phthalocyanine, as blue, green, or red sensitive photoconductive materials, respectively. The spectral photoresponse characteristics were measured, and the output signal from each detector showed good spectral selectivity, clearly demonstrating color separation in the vertically stacked structure. Comparisons of the output signal currents of single structures (without stacking) and the stacked structure revealed that 70% of the incident light reached the bottom layer of the stack.
A color image was produced by a vertically stacked image sensor with blue (B)-, green (G)-, and red (R)-sensitive organic photoconductive films, each having a thin-film transistor (TFT) array that uses a zinc oxide (ZnO) channel to read out the signal generated in each organic film. The number of the pixels of the fabricated image sensor is 128 Â 96 for each color, and the pixel size is 100 Â 100 m 2 . The current on/off ratio of the ZnO TFT is over 10 6 , and the B-, G-, and R-sensitive organic photoconductive films show excellent wavelength selectivity. The stacked image sensor can produce a color image at 10 frames per second with a resolution corresponding to the pixel number. This result clearly shows that color separation is achieved without using any conventional color separation optical system such as a color filter array or a prism.
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