As a biomass utilization techno]ogy, methanol er ]iquid fue] synthesis system applying proprietary gasifief and catalyst synthesis technolegy has been deve]oped, In a test equipment opcration, methanol was successfully derived and influence of gasification condition on conversion efficiency was verified.Dernenstration plant project was staTted in 2001 as an R&D national projcct. This mukes it possible to use renewable energy in the mobile and transportation fields.
The active sites for the hydrodenitrogenation of carbazole for a series of low loading nitrided Mo/Al 2 O 3 catalysts have been investigated by a combination of CO adsorption, pyridine adsorption, temperature-programmed surface reaction with hydrogen and fractal analysis. Accordingly, the active sites for different stages of reaction have been determined. It is proposed that carbazole adsorbs on the edge of molybdenum nitride crystallites where it is hydrogenated to perhydrocarbazole which desorbs, migrating to nitrogen deficient nitrogen planes where it undergoes C-N hydrogenolysis.
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