Photodetachment of the positronium negative ion, a bound state of one positron and two electrons, has been observed. Development of a method to produce the ions efficiently using a Na coated tungsten surface has enabled the first observation of the photodetachment. The obtained lower limit of the photodetachment cross section for the wavelength of 1064 nm is consistent with the theoretical calculations reported so far. The experimental field developed in the present work gives new opportunities to explore the quantum mechanical three-body problem and to develop energy-tunable positronium beams.

The emission of positronium negative ions from Na-and K-coated W(100) surfaces has been studied. The emission efficiencies (the fractions of incident slow positrons yielding the ions) for both samples were found to be as high as 1.5%. Although the efficiencies decreased with time after coating, the effects were more durable than that for Cs coating. In particular, the efficiency after Na coating was still higher than 0.5% after three days. The successful development of a durable Ps − source opens the door to a new era of experimental investigations on the Ps − ion.

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