Summary In this study, sewage was simultaneously treated and used to produce electricity using a two‐chambered microbial fuel cell (MFC) with carbon cloth electrodes having platinum coating on the cathode. Porous carbon electrodes are found to be the more suitable for MFCs as the power generation value is high when compared with nonporous surfaces and has a significant impact on the development of stable biofilms on the anode. Wastewater having an initial chemical oxygen demand (COD) of 830 ± 20 mg/L had a removal efficiency from the MFC of around 78%. The initial pH of sewage in the range of 7.69 ± 0.2 saw a shift towards neutral (around 7.4) and biochemical oxygen demand ranging from 300 ± 20 mg/L in the system decreased up to 175 ± 15 mg/L. The cell open circuit voltage peaked at 800 mV. Current and power density was calculated using an external resistance (of 250 Ω) followed by normalizing to the anode surface area. This bioelectricity generation is attributed to the decomposition of the organic matter and is reported to peak at 0.54 mA/m2 and 204 ± 0.38 mW/m2, respectively. Power generation has faster COD removal rates with external resistors compared with open circuit analysis, and MFCs can be effective to support the wastewater treatment infrastructure while at the same time generate electrical power as a value added product.
With the increasing demand for clean hydrogen production, both as a fuel and an indispensable reagent for chemical industries, acidic water electrolysis has attracted considerable attention in academic and industrial research. Iridium is a well-accepted active and corrosion-resistant component of catalysts for oxygen evolution reaction (OER). However, its scarcity demands breakthroughs in catalyst preparation technologies to ensure its most efficient utilization. This minireview focusses on the wet-chemistry synthetic methods of the most active and (potentially) durable Ir catalysts for acidic OER, selected from the recent publications in the open literature. The catalysts are classified by their synthesis methods, with authors' opinion on their practicality. The review may also guide the selection of the state-of-the-art Ir catalysts for benchmarking purposes.
Development of an active and durable catalyst for oxygen evolution reaction (OER) is a pivotal part of designing an efficient PEM water electrolyser. Iridium is one of the best available catalysts because of its corrosion resistance and activity [1]. Use of Ir is however, limited by its scarcity, limited durability and high cost. Its deposition on a support is a popular way to improve the available surface area, activity and stability [2]. For applications in acidic water electrolysis, supports with the highest chemical resistance and conductivity are preferred. While different methods have been studied to impregnate a support with catalyst nanoparticles, such as Adams’s fusion method and polyol method, their scalability remains questionable due to intensive resource requirements. In this work, Ir oxide based supported catalysts have been synthesized using the incipient wetness method (IWM), one of the most commonly used method of catalyst synthesis in the industry due to its ease of scalability, limited resource requirement and the opportunity to explore the effect of strong metal support interactions. This method however has not been discussed in literature. In this study, Ir oxide (IrOx) (Ir loading on support = 20 wt. percent) was dispersed on commercial supports (ZrO2, Nb2O5, Ta2O5, ATO) using H2IrCl6.xH2O precursor (99.9% trace metal basis, Sigma Aldrich). The catalysts were calcined at 400oC for 2 h in a muffle furnace to produce Ir oxide based catalysts. Electrochemical measurements were carried out on a standard rotating-disk electrode (RDE) system (PINE Research MSR Rotator), and a three-electrode electrochemical cell in 1.0 M sulfuric acid electrolyte (H2SO4 optima grade, Fisher Scientific). The performance of the aforementioned supported Ir oxide catalyst was compared among themselves, and to benchmark commercial catalysts (Umicore Ir Black and IrOx TKK) using metrics such as mass normalized activity (A/g-1 Ir), ECSA normalized activity (mA/cm2 Ir ECSA), Tafel slope (mV/dec) and charge transfer resistance (Rct) measured during the electrochemical test. It was observed that the activity of IrOx/ZrO2 (415 A/gIr, 5.2 mA/cm2 Ir ECSA) was the best among all the 4 impregnated catalysts, and was in fact, more than an order of magnitude greater than that of IrOx/ATO (30 A/gIr, 0.3 mA/cm2 Ir ECSA) at a potential of 1.53 VRHE. A significant drop in the Tafel slope measured in the potential range of 1.45-1.55 VRHE was observed upon changing the support from ATO (80 mV/dec) to ZrO2 (60 mV/dec) hinting towards a change in the reaction mechanism. IrOx/ATO was used as a baseline due to prevalent recognition of ATO as an excellent support for OER catalysts in the literature. Upon comparison with commercial benchmark catalysts it was observed that the Ir ECSA normalized activity of IrOx/Nb2O5, IrOx/Ta2O5, IrOx/ZrO2 surpasses both Umicore Ir black ( 2.23 mA/cm2 Ir ECSA) and IrOx TKK (1.23 mA/cm2 Ir ECSA) with IrOx/ZrO2 providing the highest activity. While Yttria-stabilized zirconia (YSZ) has been a popular choice as an electrolyte and anode for high temperature SOFC due to its non-reducing nature, high thermal stability and mechanical strength, and acceptable oxygen ion conductivity [3], its application in PEM water electrolysis as catalyst support has not been discussed. In this work, we focus on finding the causes for superior performance of ZrO2 as a support for Ir oxide based OER reaction in acidic conditions through the lens of electrocatalysis. References: [1] X. Li, X. Hao, A. Abudula, and G. Guan, “Nanostructured catalysts for electrochemical water splitting: Current state and prospects,” Journal of Materials Chemistry A, vol. 4, no. 31, pp. 11973–12000, 2016, doi: 10.1039/c6ta02334g. [2] H. Dhawan, M. Secanell, and N. Semagina, “State-of-the-art iridium-based catalysts for acidic water electrolysis: a minireview of wet-chemistry synthesis methods,” Jan. 01, 2021. https://www.ingentaconnect.com/content/matthey/jmtr/pre-prints/content-jm_jmtr_semagapr21 (accessed Mar. 26, 2021). [3] T. K. Maiti et al., “Zirconia- and ceria-based electrolytes for fuel cell applications: critical advancements toward sustainable and clean energy production,” Environ Sci Pollut Res, vol. 29, no. 43, pp. 64489–64512, Sep. 2022, doi: 10.1007/s11356-022-22087-9. Figure 1
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