Water-repellent and self-cleaning properties of lotus leaves are considered to be due to its double roughness structure, protrusion structure (approximately 20 microm) and hairy structure (0.2-1.0 microm). In this study, attempts to fabricate a spatially periodic double roughness structure by two far-from-equilibrium self-organization phenomena, a directional viscous fingering and a spinodal dewetting, were made. A mixture of an octylsilyl titanium dioxide particle having an average diameter of 35 nm suspended in volatile silicone, decamethyl cyclopentasiloxane, and octyl p-methoxycinnamate was spread on a glass plate by dragging an applicator across the top. Formation of a stripe pattern parallel to the direction of dragging, called directional viscous fingering, was sometimes observed. Influences of spreading conditions on the pattern formation were analyzed. In addition, attempts were made to apply the stripe pattern formation to the preparation of a water repellent surface. We have succeeded in preparing a highly water-repellent surface by immersing a glass plate, on which a spatially periodic stripe pattern having a characteristic wavelength of 200-700 microm was formed, in water, after the completion of evaporation of decamethyl cyclopentasiloxane. In this case, dewetting patterns having a characteristic wavelength at around 5 microm were formed at the bottom part of the stripe patterns. Neither the surface on which only the mesoscopic spatially periodic stripe pattern was formed nor the one on which only the microscopic dewetting pattern was formed showed high water-repellent properties, indicating that the coexistence of the two different scales of patterns increased the water-repellent properties of the hydrophobic surface.
An organic-inorganic hybrid composite for use as a coating agent was prepared by mixing linseed oil with hydrophobic octylsilyl titanium dioxide particles having an average diameter of 35 nm (OSI-TIO2-35) in volatile silicone. The weight ratio of linseed oil with OSI-TIO2-35 was varied from 2:8 to 8:2 and the mixture was spread on a glass plate by dragging an applicator across it. After storing in the oven at 60°C for 2 days, the composite having the weight ratio of OSI-TIO2-35 with linseed oil at 8:2 exhibited very high water-repellent properties having a water contact angle of 148°. Variation of the water contact angle during storage at 60°C was monitored. It decreased by 10°in the initial 8 h and then increased by 45°over the next 2 days. Composites containing silicone resin, TMSS BY11-018, instead of linseed oil were also prepared. The sample having a weight ratio of OSI-TIO2-35 with TMSS BY11-018 at 8:2 also exhibited very high water-repellent properties with a water contact angle of 152°. The highly hydrophobic surface thus prepared by the coating and drying of those organic-inorganic hybrid composites was easily transferred to highly hydrophilic surfaces by calcination at 500°C for 3 h.
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