Electrochemical carboxylation of alkyl-substituted vinyl bromides (1a-1g) in the presence of 20 mol% of NiBr2•bpy under an atmospheric pressure of carbon dioxide with a platinum cathode and a magnesium anode gave the corresponding α,β-unsaturated carboxylic acids (2a-2g) in yields of 53-82%.
Little work on the void fraction behaviors along structural materials with poor-wettability for liquid metals has been performed. In the present study, void fraction behaviors around a single cylinder with non-wetting surface condition were quantitatively discussed by using a gas jet-cylinder system where the impinging jet flow, the boundary layer flow, the separation flow, and the wake flow appear. One cylinder with a non-wetting surface and two cylinders with a wetting surface were used to vary the wettability for liquid sodium, and void fraction distributions were measured around the cylinders. In the case of wetting condition, void fraction distributions around the cylinder decrease clearly in the backward region of the cylinder, and liquid-rich region is formed due to bubble separation from the cylinder surface. On the other hand, under non-wetting condition, because of two-phase flow without bubble separation on the cylinder surface, void fraction distributions show almost steady values around the cylinder compared to those with wetting surface. The void behaviors on a non-wetting surface were also confirmed by a visualization experiment conducted in water. The observed differences can be basically attributed to the work of adhesion required for liquid-solid interfacial separation.
We report the formation of spherulites from droplets of highly concentrated tubulin solution via nucleation and subsequent polymerization to microtubules (MTs) under water evaporation by heating. Radial alignment of MTs in the spherulites was confirmed by the optical properties of the spherulites observed using polarized optical microscopy and fluorescence microscopy. Temperature and concentration of tubulins were found as important parameters to control the spherulite pattern formation of MTs where evaporation plays a significant role. The alignment of MTs was regulated reversibly by temperature induced polymerization and depolymerization of tubulins. The formation of the MTs patterns was also confirmed at the molecular level from the small angle X-ray measurements. This work provides a simple method for obtaining radially aligned arrays of MTs.
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