Measurements of trace gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbour, Venus, has cloud decks that are temperate but hyperacidic. Here we report the apparent presence of phosphine (PH 3) gas in Venus's atmosphere, where any phosphorus should be in oxidized forms. Single-line millimetre-waveband spectral detections (quality up to ~15σ) from the JCMT and ALMA telescopes have no other plausible identification. Atmospheric PH 3 at ~20 ppb abundance is inferred. The presence of PH 3 is unexplained after exhaustive study of steady-state chemistry and photochemical pathways, with no currently known abiotic production routes in Venus's atmosphere, clouds, surface and subsurface, or from lightning, volcanic or meteoritic delivery. PH 3 could originate from unknown photochemistry or geochemistry, or, by analogy with biological production of PH 3 on Earth, from the presence of life. Other PH 3 spectral features should be sought, while in situ cloud and surface sampling could examine sources of this gas.

Abstract. This paper describes the algorithms of the level-2 research (L2r) processing chain developed for the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES). The chain has been developed in parallel to the operational chain for conducting researches on calibration and retrieval algorithms. L2r chain products are available to the scientific community. The objective of version 2 is the retrieval of the vertical distribution of trace gases in the altitude range of 18-90 km. A theoretical error analysis is conducted to estimate the retrieval feasibility of key parameters of the processing: line-of-sight elevation tangent altitudes (or angles), temperature and ozone profiles. While pointing information is often retrieved from molecular oxygen lines, there is no oxygen line in the SMILES spectra, so the strong ozone line at 625.371 GHz has been chosen. The pointing parameters and the ozone profiles are retrieved from the line wings which are measured with high signal to noise ratio, whereas the temperature profile is retrieved from the optically thick line center. The main systematic component of the retrieval error was found to be the neglect of the non-linearity of the radiometric gain in the calibration procedure. This causes a temperature retrieval error of 5-10 K. Because of these large temperature errors, it is not possible to construct a reliable hydrostatic pressure profile. However, as a consequence of Correspondence to: P. Baron (baron@nict.go.jp) the retrieval of pointing parameters, pressure induced errors are significantly reduced if the retrieved trace gas profiles are represented on pressure levels instead of geometric altitude levels. Further, various setups of trace gas retrievals have been tested. The error analysis for the retrieved HOCl profile demonstrates that best results for inverting weak lines can be obtained by using narrow spectral windows.

We present distributions of the zonal-mean temperature and static stability in the Venusian atmosphere obtained from Venus Express and Akatsuki radio occultation profiles penetrating down to an altitude of 40 km. At latitudes equatorward of 75°, static stability derived from the observed temperature profiles is consistent with previous in-situ measurements in that there is a low-stability layer at altitudes of 50-58 km and highly and moderately stratified layers above 58 km and below 50 km, respectively. Meanwhile, at latitudes poleward of 75°, a low-stability layer extends down to 42 km, which has been unreported in analyses of previous measurements. The deep low-stability layer in the polar region cannot be explained by vertical convection in the middle/lower cloud layer, and the present result thus introduces new constraints on the dynamics of the sub-cloud atmosphere. The Venusian atmosphere is in striking contrast to the earth's troposphere, which generally has a deeper low-stability layer at low latitudes than at mid-and high latitudes. The dynamics of the Venusian atmosphere remain unclear because Venus is completely globally covered by thick clouds at altitudes of 48-70 km. The thermal structure of the Venusian atmosphere across this cloud layer is important in terms of understanding aspects of the general circulation, such as the mean meridional circulation and baroclinic instability waves, which contribute to meridional heat transport and atmospheric super-rotation. In-situ measurements were made by entry probes around the equator and 60°N as part of the Venera and Pioneer Venus missions, revealing a low-stability (weakly or almost neutrally stratified) layer at an altitude of approximately 50-55 km, a highly stratified layer above 55 km and a moderately stratified layer below 50 km 1. Radio occultation measurements, one of the most useful methods of obtaining vertical temperature profiles, were made as part of the National Aeronautics and Space Administration's (NASA's) Pioneer Venus mission and the European Space Agency's (ESA's) Venus Express mission 2-4 to obtain latitude-height distributions of temperature. These observations revealed that a cold latitudinal band called a "cold collar", which is thought to be formed by dynamics 5 and/or the latitudinal cloud structure 6 , is located at roughly 65° latitude near the cloud top (at nearly 65 km altitude) and surrounds a warm polar region and that temperature increases with latitude above 65 km and decreases with latitude below 60 km. Furthermore, static stability profiles obtained from the Venus Express radio occultation measurements showed that the low-stability layer in the cloud layer is deeper at high latitudes than at low and mid-latitudes 4. However, no in-situ measurements have been made at latitudes poleward of 60°, and the thermal structure below the cloud layer at high latitudes thus remains unknown.

Abstract. Chlorine monoxide (ClO) is the key species for anthropogenic ozone losses in the middle atmosphere. We observed ClO diurnal variations using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the International Space Station, which has a non-sunsynchronous orbit. This includes the first global observations of the ClO diurnal variation from the stratosphere up to the mesosphere. The observation of mesospheric ClO was possible due to 10-20 times better signal-to-noise (S/N) ratio of the spectra than those of past or ongoing microwave/submillimeter-wave limb-emission sounders. We performed a quantitative error analysis for the strato-and mesospheric ClO from the Level-2 research (L2r) product version 2.1.5 taking into account all possible contributions of errors, i.e. errors due to spectrum noise, smoothing, and uncertainties in radiative transfer model and instrument functions. The SMILES L2r v2.1.5 ClO data are useful over the range from 0.01 and 100 hPa with a total error estimate of 10-30 pptv (about 10 %) with averaging 100 profiles. The SMILES ClO vertical resolution is 3-5 km and 5-8 km for the stratosphere and mesosphere, respectively. The SMILES observations reproduced the diurnal variation of stratospheric ClO, with peak values at mid-

We report on the initial analysis of a Herschel-PACS full range spectrum of Neptune, covering the 51-220 μm range with a mean resolving power of ∼3000, and complemented by a dedicated observation of CH 4 at 120 μm. Numerous spectral features due to HD (R(0) and R(1)), H 2 O, CH 4 , and CO are present, but so far no new species have been found. Our results indicate that (i) Neptune's mean thermal profile is warmer by ∼3 K than inferred from the Voyager radio-occultation; (ii) the D/H mixing ratio is (4.5 ± 1) × 10 −5 , confirming the enrichment of Neptune in deuterium over the protosolar value (∼2.1 × 10 −5 ); (iii) the CH 4 mixing ratio in the mid stratosphere is (1.5 ± 0.2) × 10 −3 , and CH 4 appears to decrease in the lower stratosphere at a rate consistent with local saturation, in agreement with the scenario of CH 4 stratospheric injection from Neptune's warm south polar region; (iv) the H 2 O stratospheric column is (2.1 ± 0.5) × 10 14 cm −2 but its vertical distribution is still to be determined, so the H 2 O external flux remains uncertain by over an order of magnitude; and (v) the CO stratospheric abundance is about twice the tropospheric value, confirming the dual origin of CO suspected from ground-based millimeter/submillimeter observations.