Hideo Imoto scite author profile

ChemInform Abstract The title complex (II) is prepared as shown by reductive dimerization of (I), which is a new class of cluster condensation. (II) crystallizes in the space group R3 with Z=3 and has 20 cluster valence electrons. The cluster possesses a regular octahedral core of six Mo atoms. The cyclic voltammetry and coulometry in CH2Cl2 solution indicate reversible one-electron reduction and oxidation waves.

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Molecular models of the superconducting chevrel phases: syntheses and structures of [Mo6X8(PEt3)6] and [PPN][Mo6X8(PEt3)6] (X = S, Se; PPN = (Ph3P)2N)

Saito¹,

Yamamoto²,

Nagase³

et al. 1990

Inorg. Chem.

107

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Synthesis of covellite (CuS) from the elements

Tezuka

Sheets

Kurihara

et al. 2007

Solid State Sciences

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Performance and Characterization of a New Crystalline SbRe2O6 Catalyst for Selective Oxidation of Methanol to Methylal

Yuan

Liu

Imoto

et al. 2000

Journal of Catalysis

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Synthesis, structure and electronic properties of octakis(.mu.3-sulfido)hexakis(triethylphosphine)hexatungsten as a tungsten analog of the molecular model for superconducting Chevrel phases

Saito¹,

Yoshikawa²,

Yamagata³

et al. 1989

Inorg. Chem.

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Hideo Imoto

Synthesis of [Mo6S8(PEt3)6] by reductive dimerization of a trinuclear molybdenum chloro sulfido cluster complex coordinated with triethylphosphine and methanol: a molecular model for superconducting Chevrel phases

Molecular models of the superconducting chevrel phases: syntheses and structures of [Mo6X8(PEt3)6] and [PPN][Mo6X8(PEt3)6] (X = S, Se; PPN = (Ph3P)2N)

Synthesis of covellite (CuS) from the elements

Performance and Characterization of a New Crystalline SbRe2O6 Catalyst for Selective Oxidation of Methanol to Methylal

Synthesis, structure and electronic properties of octakis(.mu.3-sulfido)hexakis(triethylphosphine)hexatungsten as a tungsten analog of the molecular model for superconducting Chevrel phases

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