A new process has been developed to reduce excess sludge production, in which both excess sludge digestion and wastewater treatment are conducted simultaneously in the same aeration tank. The ozonation enhances biological degradation of the activated sludge, which is decomposed in a subsequent biological treatment. A considerable amount of biomass is mineralized biologically in proportion to the amount of recirculated biomass from the ozonation stage to the biological stage. It was observed that the amount of excess sludge is reduced to nearly zero when 1.2 kg/m3-aeration tank volume of biomass is recirculated in a day from the biological stage to the ozonation stage at a BOD loading of 1.0 kg/m3/d. A biomass concentration of 4200 mg/L was maintained at 1.0 kg-BOD/m3/d without drawing excess sludge for 6 weeks of experimental period under ozone dose of 0.05 g-O3/g-SS and recirculation rate at 0.3 d−1. Only a limited difference in the effluent quality was observed between the new process and the conventional activated sludge process.
The authors have presented a new concept of excess sludge elimination treatment with recirculation of sludge via ozonation in the activated sludge process. This paper is intended to clarify the potential application of the process to municipal and industrial wastewater treatments. In a full-scale operational experiment lasting 10 months under 550 kg/d of BOD loading, no excess sludge was needed to be withdrawn and no significant accumulation of inorganic solids occurred in the aeration tank. Most of the inorganic compounds in the sludge were released to the soluble phase. Material balance indicated that one-third of ozonated sludge was mineralized via the recirculation treatment, and thereby the requirement of sludge mass to be treated was 3.3 times as much as sludge to be eliminated. Effluent TOC was slightly higher than under the conventional activated sludge process, indicating that refractory TOC was released from the sludge eliminated by treatment. The amount of released TOC corresponded to less than 2 weight % of eliminated sludge under recirculation rates below 30% of total biomass in the aeration tank in a day, but increased at higher recirculation rates. The operation costs associated with the process were estimated to be lower than those of conventional dewatering and disposal.
An activated sludge process which produces no excess sludge was developed. The process is very simple as a small amount of return sludge is ozonated and then returned to the aeration tank. The ozonation enhances biodegradability of activated sludge, which is biologically oxidized in the aeration tank. A full-scale plant for treating 450m3/d of municipal wastewater was constructed and has been operated successfully for 9 months. The amount of excess sludge eliminated is directly proportional to the amount of ozone dosed to the sludge. At the ozone dosing rate of 0.034 kg/kg-SS, complete elimination of excess sludge has been achieved when 4 times more amount of sludge is ozonated than that of the excess sludge expected in the treatment without ozonation. After 5 months of operation without any withdrawal of excess sludge, small amount of inorganic substances like sand and silt accumulated in the sludge. On the other hand, inert organic substances does not seem to accumulate. As for effluent quality, BOD and nitrogen were kept good. Although effluent SS was 2–15 mg/l higher compared to a control without ozonation, it has been well below the discharge limit.
Source minimization of excess sludge production by economical means can be considered an attractive option to deal with the problem of sludge disposal under strict disposal standards. In this paper long-term operational results for a process that combines the oxidative ozone pretreatment with anaerobic sludge digestion are described. The ozone pretreatment solubilized around 19% and 37% of the solids at 0.015 and 0.05 gO3/gTS ozone dose. The solubilization ratios during ozonation did not show any significant difference for the sludge concentrations ranging from 1.8-2.6%. The TVS concentrations after ozone treatment were observed to be about 3% lower than the feed sludge concentrations suggesting only partial mineralization during ozonation. The ozone pretreatment resulted in improved solid reduction efficiencies during anaerobic digestion leading to higher methane recovery. The TVS removal efficiencies during anaerobic digestion were observed to increase by a maximum of 35-90% depending on the applied ozone dose during ozone pretreatment. The improvement in TVS degradation efficiency at different applied ozone doses correlated well with the extent of solubilization during ozonation. Long-term data also suggested that biomass acclimation to ozonated sludge was necessary before higher degradation efficiencies could be achieved.
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