Thanks to low costs and the abundance of the resources, sodium‐ion (SIBs) and potassium‐ion batteries (PIBs) have emerged as leading candidates for next‐generation energy storage devices. So far, only few materials can serve as the host for both Na+ and K+ ions. Herein, a cubic phase CuSe with crystal‐pillar‐like morphology (CPL‐CuSe) assembled by the nanosheets are synthesized and its dual functionality in SIBs and PIBs is comprehensively studied. The electrochemical measurements demonstrate that CPL‐CuSe enables fast Na+ and K+ storage as well as the sufficiently long duration. Specifically, the anode delivers a specific capacity of 295 mA h g−1 at current density of 10 A g−1 in SIBs, while 280 mA h g−1 at 5 A g−1 in PIBs, as well as the high capacity retention of nearly 100% over 1200 cycles and 340 cycles, respectively. Remarkably, CPL‐CuSe exhibits a high initial coulombic efficiency of 91.0% (SIBs) and 92.4% (PIBs), superior to most existing selenide anodes. A combination of in situ X‐ray diffraction and ex situ transmission electron microscopy tests fundamentally reveal the structural transition and phase evolution of CuSe, which shows a reversible conversion reaction for both cells, while the intermediate products are different due to the sluggish K+ insertion reaction.

In article number https://doi.org/10.1002/aenm.201900323, Yi Zeng, Fei Du and co‐workers report the synthesis of a novel cubic phase CuSe crystal pillar which is self‐assembled by nanosheets, together with the dual functionality for high‐rate Na+ and K+ storage. A combination of in‐situ X‐ray diffraction and ex‐situ transmission electron microscopy tests, reveal the structural transition and phase evolution of CuSe that show a reversible conversion reaction for both cells.

Potassium-ion batteries (PIBs) have been deemed as a promising alternative of lithium-ion batteries (LIBs) for the next-generation energy storage due to the abundance and the competitive cost of potassium resources....

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