The Penouta Sn-Ta deposit, in the northwest of Spain, is a greisenized granitic cupola where Ta minerals occur mainly as disseminations in a leucogranite body intruded in Precambrian–Lower Cambrian gneisses and mica-schists. This leucogranite is a medium- to fine-grained inequigranular rock consisting mainly of quartz, albite, K-feldspar and muscovite. Accessory minerals are mainly of spessartine, zircon, cassiterite, Nb-Ta oxides, monazite, xenotime, native bismuth and pyrite. The alteration processes were mainly albitization, muscovitization and kaolinitization.This leucogranite is peraluminous and P-poor, with 0.03–0.07 wt.% P2O5, 900–1500 ppm Rb, 30–65 ppm Cs, 120–533 ppm Li, 80–140 ppm Ta, 51–81 ppm Nb and up to 569 ppm of Sn.Mineralogical characterization of Nb-Ta oxide minerals was determined by X-ray diffraction, scanning electron microscopy, electron microprobe analysis and mineral liberation analysis. Mn-rich members of the columbite-group minerals (CGM) are the most common Ta-bearing phases, but microlite, wodginite, tapiolite and Ta-rich cassiterite occur also. CGM crystals are commonly zoned concentrically, with a Nb-rich core surrounded by a Ta-rich rim, with a sharp boundary between them. Convoluted zoning occurs also. Dissolution textures resulting from the corrosion of columbite and tantalite rims, in particular, are common. The Mn/(Mn + Fe) ratio varies between 0.33 and 0.97 and the Ta/(Ta + Nb) ratio between 0.07 and 0.93. Wodginite and microlite formed as late replacements of CGM and occur associated with tantalite and cassiterite. Subhedral to anhedral cassiterite crystals, usually up to 200 μm across, occur in two generations: the earlier one is Nb,Ta-poor whereas in the later generation, the Ta content can reach >9 wt.% of Ta2O5 and 1.7 wt.% of Nb. The presence of a fluid phase in the apical zone of the granite, probably related to the separation of a fluid/vapour of the melt, could explain the sponge-like textures, the Ta enrichment associated with these textures, the occurrence of Ta-enriched mineral phases (microlite and wodginite) and their common interstitial character.

Abstract:The modelling of high pressure grinding rolls is described by the population balance model, a mass balance which includes several functions that are related to the mineral characteristics, material kinetics and operative conditions of the device. The breakage distribution function is one of these functions and refers to the way in which the daughter particles are generated by the process of comminution. The piston-die press is presented as a methodology to determine the breakage distribution function of two different materials, from the mechanical response point of view: altered granite and a cal-silicate material. The aim is to determine the relation between the operative conditions and the mineral characteristics in order to explain and predict the breakage function parameters. The materials were characterised using XRD and single compression strength tests. The altered granite is a brittle material, which generates more fines under single compression conditions compared to bed compression conditions, mainly due to the mineral composition and the response of the material to the breakage action. The cal-silicate material shows a normal trend in its breakage behaviour. As is expected, the mineralogical characterisation is a useful tool to predict the values of the parameters of the breakage distribution function.

An analysis of occupational accidents in the mining sector was conducted using the data from the Spanish Ministry of Employment and Social Safety between 2005 and 2015, and data-mining techniques were applied. Data was processed with the software Weka. Two scenarios were chosen from the accidents database: surface and underground mining. The most important variables involved in occupational accidents and their association rules were determined. These rules are composed of several predictor variables that cause accidents, defining its characteristics and context. This study exposes the 20 most important association rules in the sector—either surface or underground mining—based on the statistical confidence levels of each rule as obtained by Weka. The outcomes display the most typical immediate causes, along with the percentage of accidents with a basis in each association rule. The most important immediate cause is body movement with physical effort or overexertion, and the type of accident is physical effort or overexertion. On the other hand, the second most important immediate cause and type of accident are different between the two scenarios. Data-mining techniques were chosen as a useful tool to find out the root cause of the accidents.

Abstract:The mineralogy and liberation characteristics of the comminuted Penouta leucogranite host of the Sn-Ta ore were determined. Grinding developed by a combination of high-pressure grinding rolls (HPGR) followed by a ball mill (BM) was compared with a single ball mill process. The mineral characteristics of the grinding products were analyzed using a Tescan Integrated Mineralogical Analyzer (TIMA-X) and X-ray powder diffraction (XRD). The ore contains 103 ppm of Ta and is mainly composed of quartz, albite, microcline, muscovite, and kaolinite. Nb, Ta-rich minerals are columbite-(Mn) and tantalite-(Mn), as well as minor microlite and wodginite. The liberation in the product is high in the size fraction of less than 250 µm (51-52 wt % for columbite-group minerals (CGM) and 74-80 wt % for cassiterite) and reduced in larger particles (8.8-17 wt % for CGM and 28-37 wt % for cassiterite). The recovery in the −250 µm fraction was high, while in the larger fraction it is limited, remaining up to 80 ppm in some tailings. The combined use of HPGR and a BM reduces the particle size distribution of the product and, thus, increases the liberation of the ores. Smaller fractions can be treated directly using gravity methods; however, particles of a size greater than +250 µm should be ground more.

Mineralogy and gold processing techniques from several mining areas of the Nazca-Ocoña gold belt, Mid-South Peru, were investigated to assess the efficiency of gold extraction methods in relation to their mineralogy. The deposits from this belt are intrusion gold related to mineralization in quartz veins. Native gold occurs as micrometric grains encapsulated in pyrite and in minor amounts in other sulfides and quartz. Electrum is found mainly in fractures of pyrite and attains up to 35 wt. % Ag. In addition to these occurrences, gold tellurides also occur and they are abundant in San Luis. Gold processing is carried out by amalgamation with mercury and/or cyanidation. The comparison of the gold grade in the mineralizations and in the residual tailings indicates that a significant amount of gold is not recovered using the mercury amalgamation process and also, in the case of the gold recovery by cyanidation, except when cement was added to the cyanide solution. This was due to an increase in the pH that favours the dissolution of the gold matrix. In the cyanidation process carried out in tailings previously treated with mercury, part of the mercury retained in them is released to the atmosphere or to the cyanidation fluids.

The strategic importance of tantalum and its scarcity in Europe makes its recovery from low grade deposits and tailings interesting. In Penouta, the contents of Ta and Sn in old tailings from an Sn mine are of economic interest. Due to the relatively low grade of Ta of around 100 ppm, a detailed study of the mineralogy and liberation conditions is necessary. In this study, the mineralogy and the liberation characteristics of Sn and Ta ores of the Penouta tailings were investigated and compared with the current leucogranite outcropping ores. The characterization was conducted through X-ray diffraction, scanning electron microscopy, and electron microprobe. In addition, automated mineralogy techniques were used to determine the mineral associations and liberation characteristics of ore minerals. The grade of the leucogranite outcropping was found to be about 80 ppm for Ta and 400 ppm for Sn, and in the tailings used for the liberation study, the concentrations of Ta and Sn were about 100 ppm Ta and 500 ppm Sn, respectively. In both, the leucogranite outcropping and tailings, the major minerals found were quartz, albite, K-feldspar, and white mica. Ore minerals identified were columbite-group minerals (CGM), microlite, and cassiterite. The majority of CGM examined were associated with cassiterite, quartz, and muscovite particle compositions and cassiterite was mainly associated with CGM, quartz, and muscovite. The liberation size was 180 µm for CGM.

An improved approach is presented to model the product particle size distribution resulting from grinding in high-pressure roll crusher with the aim to be used in standard high-pressure grinding rolls (HPGR). This approach uses different breakage distribution function parameter values for a single particle compression condition and a bed compression condition. Two materials were used for the experiments; altered Ta-bearing granite and a calc-silicate tungsten ore. A set of experiments was performed with constant operative conditions, while varying a selected condition to study the influence of the equipment set-up on the model. The material was comminuted using a previously determined specific pressing force, varying the feed particle size, roll speed and the static gap. A fourth group of experiments were performed varying the specific pressing force. Experimental results show the high performance of the comminution in a high-pressure environment. The static gap was the key in order to control the product particle size. A mathematical approach to predict the product particle size distribution is presented and it showed a good fit when compared to experimental data. This is the case when a narrow particle size fraction feed is used, but the fit became remarkably good with a multi-size feed distribution. However, when varying the specific pressing force in the case of the calc-silicate material, the results were not completely accurate. The hypothesis of simultaneous single particle compression and bed compression for different size ranges and with different parameters of the distribution function was probed and reinforced by various simulations that exchanged bed compression parameters over the single particle compression distribution function, and vice versa.The main advantages of HPGR lie in energy savings and the simplicity of the process [7]. However, the particle size reduction ratio is lower than that in some other types of mills, such as ball and rod mills. HPGR are used in various configurations such as pre-grinding, hybrid grinding and finish grinding, among others [4]. This is mainly due to the comminution effect under the action of high-pressure rolls, which generates many more internal fractures of particles than other devices [13][14][15], and also generates material with latent cracks for a second stage of milling or even enough to liberate the ore [4,16]. The favourable influence of HPGR performance on downstream beneficiation operations has also been proved, for example, in the ore flotation process [17]. HPGR also appears to have a less negative impact on the environment in terms of lower dust and noise emissions [18].With regard to the description of the model, the mechanism of breakage by compression and shear is dominant in roll crushers [19]. In HPGR, two main breakage mechanisms are observed: single particle compression and bed compression [20][21][22]. Single particle compression is more efficient, but larger particles cause unnecessary liner wear issues [21] and also result in the separatio...

There has been a long history of coal mine accidents and these, usually, involve serious injuries, fatalities, and the destruction of facilities. In the seventies, an explosion killed 28 miners in a Spanish coal mine. This paper gives insight into the main factors of the accident by means of the causation mode, using two well-known alternatives: (1) the method from the Spanish Instituto Nacional de Seguridad y Salud en el Trabajo (INSST), where the causes and circumstances of the accident are classified into immediate causes and basic causes, and (2) the Feyer and Williamson method, where the classification is done using precursor events and contributing factors. The analysis identifies the lessons to be learned from the disaster. Both methods have given very similar results, verifying the goodness of the analysis. Methane emissions due to a variation in the exploitation method, the electrical installation, and a lack of safety procedures and training were the main causes of the accident. These findings explain the real causes of this accident and can be very valuable for the prevention of future accidents.