The carbon magnetic resonance spectra of a series of C-19 hydroxy, C-5β,6β epoxy, C-5α,6α epoxy, and C-24 ethyl steroids have been assigned. Shift parameters for the C-19 hydroxyl function are listed. The data presented has led to a reassignment of the published spectra of several C5α,6 α epoxy steroids. In addition, 13Cmr spectral data for several bicyclic enones and a Δ5(10)-3-estrone are presented.
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