Gas- and plasma-driven hydrogen permeation through GaInSn/Fe have been systematically investigated in this work. The permeation parameters of hydrogen through GaInSn/Fe, including diffusivity, Sieverts’ constant, permeability and surface recombination coefficient were obtained. The permeation flux of hydrogen through GaInSn/Fe shows a great dependence on external conditions such as temperature, hydrogen pressure, and thickness of liquid GaInSn. What’s more, the hydrogen permeation behavior through GaInSn/Fe is in good agreement with the multilayer permeation theory. In PDP and GDP experiments, hydrogen through GaInSn/Fe satisfies the diffusion-limited regime. In addition, the permeation flux of PDP is greater than that of GDP. The increase of hydrogen plasma density hardly causes the change of hydrogen PDP flux within the test scope of this work, which is due to the dissolution saturation. These findings provide guidance for a comprehensive and systematic understanding of hydrogen isotope recycling, permeation, and retention in plasma-facing components under actual conditions.
The net erosion yield of CX-2002U carbon fiber composites under high-flux low-temperature hydrogen plasma is investigated using a linear plasma device. It is found that the net erosion yield decreases rapidly first, and then tends to saturate with the increase of hydrogen–plasma flux. When the temperature of the sample eroded by hydrogen plasma is above 300 °C, the hybridization of electrons outside the carbon atom would change. Then the carbon atoms combine with hydrogen atoms to form massive spherical nanoparticles of hydrocarbon compounds and deposit on the surface at the flux condition of 1.77 × 1022 m−2·s−1. Under the irradiation of hydrogen plasma loaded with negative bias, the surface morphology of the matrix carbon is changed dramatically. Moreover, the energy dependence of mass loss does not increase in proportion to the increase of hydrogen–plasma energy, but reaches a peak around 20 V negative bias voltage. Based on the analysis of different samples, it can be concluded that the enhancement of energy could make a contribution to chemical erosion and enlarge the size of pores existing on the surface.
This study examined the effects of plasma irradiation on an unwetted liquid lithium-based capillary porous system (Li-CPS). The Li-CPS was irradiated with high-density Ar plasma using a linear plasma device at Sichuan University for Plasma Surface Interaction (SCU-PSI). The high-speed camera, Langmuir probe, and multi-channel spectrometer were used to characterize the effects of plasma irradiation. Upon Ar plasma irradiation, liquid Li drops were formed on the surface of the unwetted Li-CPS. Immediately after this irradiation, the drops fractured and were ejected into the plasma within ~20 ms scale, which is not observed before to the best of our knowledge. Related results showed that the ejection behavior of Li could effectively cool electron temperature and reduce incident heat flux by ~30% and correspondingly matrix temperature ~150 °C, revealing an enhanced vapor shielding effect. The involved internal mechanism and physical processes deserve further investigations.
In this paper, an embedded multichannel capillary porous system (EM-CPS) was designed and fabricated with 304 stainless steel using the laser ablation method. The EM-CPS revealed its excellent ability to wick liquid lithium to its surface effectively. The interaction between Li-prefilled EM-CPS and plasma was studied, and the results showed that the surface temperature decreased by ~140 °C compared with the results of the experiment of EM-CPS without lithium filling. Additionally, EM-CPS displayed a better heat transfer performance and stronger radiation loss of the vapor cloud than the traditional woven tungsten-based meshes. In addition, the drift of the lithium vapor cloud center was found during plasma irradiation and led to a decrease in the intensity of the Li 670.78 nm emission line detected by the spectrometer at the observation point. When the thermal load deposited on the sample surface is reinforced by increasing the magnetic field, the rise in surface temperature is restrained due to the enhanced heat dissipation capability of lithium. SEM images of irradiated samples showed that the 304 stainless steel-based EM-CPS has corrosion problems due to the interaction between liquid lithium and argon plasma, but it still showed good plasma-facing characteristics. These findings provide a reference for further studies of embedded multichannel CPSs with plasma-facing components (PFCs) in linear plasma devices and tokamaks in the future.
The deposition of niobium film on copper with excellent superconducting property at low-temperature conditions, used as superconducting radio frequency (SRF) cavity, is a serious and urgent technical problem to be solved at present. In this work, copper-based niobium (Nb) films with a thickness of 1.5–1.8 um, regulating the deposition temperature parameters and gas flow velocity in a tube furnace, were prepared by low-temperature chemical vapor depositing (CVD) method from the reaction between H2 and Niobium chloride (NbCl5) under pure Ar atmosphere. Fabricated Nb films were characterized by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy, respectively. The results showed that the excellent crystalline quality and superconductive performance of Nb films were generated successfully by CVD at low temperatures of 650 °C–700 °C. The preparation process was optimized during deposition and the formation mechanism of Nb films was also discussed in detail. The magnetic moment versus temperature of the Nb sample prepared at 700 °C was also measured and the well-prepared Nb film deposited in the boundary layer region obtains the desired superconducting transition temperature of 9.1 K ± 0.1 K, almost equivalent to that of high pure Nb bulk material. The optimized CVD reaction method of Nb film with favorable morphology and expected superconductive property at low temperature provided a new strategy and technical process in designing the desired copper-based Nb film SRF cavity.
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