Under sustainable development conditions, the water quality of irrigation systems is a complex issue which involves the combined effects of several surface water management parameters. Therefore, this work aims to enhance the surface water quality assessment and geochemical controlling mechanisms and to assess the validation of surface water networks for irrigation using six Water Quality Indices (WQIs) supported by multivariate modelling techniques, such as Principal Component Regression (PCR), Support Vector Machine Regression (SVMR) and Stepwise Multiple Linear Regression (SMLR). A total of 110 surface water samples from a network of surface water cannels during the summers of 2018 and 2019 were collected for this research and standard analytical techniques were used to measure 21 physical and chemical parameters. The physicochemical properties revealed that the major ions concentrations were reported in the following order: Ca2+ > Na+ > Mg2+ > K+ and alkalinity > SO42− > Cl− > NO3− > F−. The trace elements concentrations were reported in the following order: Fe > Mn > B > Cr > Pb > Ni > Cu > Zn > Cd. The surface water belongs to the Ca2+-Mg2+-HCO3− and Ca2+-Mg2+-Cl−-SO42− water types, under a stress of silicate weathering and reverse ion exchange process. The computation of WQI values across two years revealed that 82% of samples represent a high class and the remaining 18% constitute a medium class of water quality for irrigation use with respect to the Irrigation Water Quality (IWQ) value, while the Sodium Percentage (Na%) values across two years indicated that 96% of samples fell into in a healthy class and 4% fell into in a permissible class for irrigation. In addition, the Sodium Absorption Ratio (SAR), Permeability Index (PI), Kelley Index (KI) and Residual Sodium Carbonate (RSC) values revealed that all surface water samples were appropriate for irrigation use. The PCR and SVMR indicated accurate and robust models that predict the six WQIs in both datasets of the calibration (Cal.) and validation (Val.), with R2 values varying from 0.48 to 0.99. The SMLR presented estimated the six WQIs well, with an R2 value that ranged from 0.66 to 0.99. In conclusion, WQIs and multivariate statistical analyses are effective and applicable for assessing the surface water quality. The PCR, SVMR and SMLR models provided robust and reliable estimates of the different indices and showed the highest R2 and the highest slopes values close to 1.00, as well as minimum values of RMSE in all models.
Assessing surface water quality for drinking use in developing countries is important since water quality is a fundamental aspect of surface water management. This study aims to improve surface water quality assessments and their controlling mechanisms using the drinking water quality index (DWQI) and four pollution indices (PIs), which are supported by multivariate statistical analyses, such as principal component analysis, partial least squares regression (PLSR), and stepwise multiple linear regression (SMLR). Twenty-two physicochemical parameters were analyzed using standard analytical methods for 55 surface water sites in the northern Nile Delta, Egypt. The DWQI results indicated that 33% of the tested samples represented good water, and 67% of samples indicated poor to unsuitable water for drinking use. The PI results revealed that surface water samples were strongly affected by Pb and Mn and were slightly affected by Fe and Cr. The SMLR models of the DWQI and PIs, which were based on all major ions and heavy metals, provided the best estimations with R2 = 1 for the DWQI and PIs. In conclusion, integration between the DWQI and PIs is a valuable and applicable approach for the assessment of surface water quality, and the PLSR and SMLR models can be used through applications of chemometric techniques to evaluate the DWQI and PIs.
Water quality has deteriorated in recent years as a result of rising population and unplanned development, impacting ecosystem health. The water quality parameters of Qaroun Lake are contaminated to varying degrees, particularly for aquatic life consumption. For that, the objective of this work is to improve the assessments of surface water quality and to determine the different geo-environmental parameters affecting the lake environmental system in Qaroun Lake utilizing the weighted arithmetic water quality index (WAWQI) and four pollution indices (heavy metal pollution index (HPI), metal index (MI), contamination index (Cd), and pollution index (PI), that are enhanced by multivariate analyses as cluster analysis (CA), principal component analysis (PCA), and support vector machine regression (SVMR). Surface water samples were collected at 16 different locations from the lake during years 2018 and 2019. Thirteen physiochemical parameters were measured and used to calculate water quality indices (WQIs). The WQIs of Qaroun Lake such WAWQI, HPI, MI, Cd, PI revealed a different degree of contamination, with respect to aquatic life utilization. The WQIs result revealed that surface water in the lake is unsuitable, high polluted, and seriously affected by pollution for an aquatic environment. The PI findings revealed that surface water samples of Qaroun Lake were significantly impacted by Al, moderately affected by Cd and Cu, and while slightly affected by Zn due to uncontrolled releases of domestic and industrial wastewater. Furthermore, increasing salinity accelerates the deterioration of the lake aquatic environment. Therefore, sewage and drainage wastewater should be treated before discharging into the lake. The SVMR models based on physiochemical parameters presented the highest performance as an alternative method to predict the WQIs. For example, the calibration (Val.) and the validation (Val.) models performed best in assessing the WQIs with R2 (0.99) and with R2 (0.97–0.99), respectively. Finally, a combination of WQIs, CA, PCA, and SVMR approaches could be employed to assess surface water quality in Qaroun Lake.
Surface water quality management is an important facet of the effort to meet increasing demand for water. For that purpose, water quality must be monitored and assessed via the use of innovative techniques, such as water quality indices (WQIs), spectral reflectance indices (SRIs), and multivariate modeling. Throughout the Rosetta and Damietta branches of the Nile River, water samples were collected, and WQIs were assessed at 51 different distinct locations. The drinking water quality index (DWQI), metal index (MI), pollution index (PI), turbidity (Turb.) and total suspended solids (TSS) were assessed to estimate water quality status. Twenty-three physicochemical parameters were examined using standard analytical procedures. The average values of ions and metals exhibited the following sequences: Ca2+ > Na2+ > Mg2+ > K+, HCO32− > Cl− > SO42− > NO3− > CO3− and Al > Fe > Mn > Ba > Ni > Zn > Mo > Cr > Cr, respectively. Furthermore, under the stress of evaporation and the reverse ion exchange process, the main hydrochemical facies were Ca-HCO3 and mixed Ca-Mg-Cl-SO4. The DWQI values of the two Nile branches revealed that 53% of samples varied from excellent to good water, 43% of samples varied from poor to very poor water, and 4% of samples were unsuitable for drinking. In addition, the results showed that the new SRIs extracted from VIS and NIR region exhibited strong relationships with DWQI and MI and moderate to strong relationships with Turb. and TSS for each branch of the Nile River and their combination. The values of the R2 relationships between the new SRIs and WQIs varied from 0.65 to 0.82, 0.64 to 0.83, 0.41 to 0.60 and 0.35 to 0.79 for DWQI, MI, Turb. and TSS, respectively. The PLSR model produced a more accurate assessment of DWQI and MI based on values of R2 and slope than other indices. Furthermore, the partial least squares regression model (PLSR) generated accurate predictions for DWQI and MI of the Rosetta branch in the Val. datasets with an R2 of 0.82 and 0.79, respectively, and for DWQI and MI of the Damietta branch with an R2 of 0.93 and 0.78, respectively. Therefore, the combination of WQIs, SRIs, PLSR and GIS approaches are effective and give us a clear picture for assessing the suitability of surface water for drinking and its controlling factors.
Agriculture has significantly aided in meeting the food needs of growing population. In addition, it has boosted economic development in irrigated regions. In this study, an assessment of the groundwater (GW) quality for agricultural land was carried out in El Kharga Oasis, Western Desert of Egypt. Several irrigation water quality indices (IWQIs) and geographic information systems (GIS) were used for the modeling development. Two machine learning (ML) models (i.e., adaptive neuro-fuzzy inference system (ANFIS) and support vector machine (SVM)) were developed for the prediction of eight IWQIs, including the irrigation water quality index (IWQI), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), potential salinity (PS), residual sodium carbonate index (RSC), and Kelley index (KI). The physicochemical parameters included T°, pH, EC, TDS, K+, Na+, Mg2+, Ca2+, Cl−, SO42−, HCO3−, CO32−, and NO3−, and they were measured in 140 GW wells. The hydrochemical facies of the GW resources were of Ca-Mg-SO4, mixed Ca-Mg-Cl-SO4, Na-Cl, Ca-Mg-HCO3, and mixed Na-Ca-HCO3 types, which revealed silicate weathering, dissolution of gypsum/calcite/dolomite/ halite, rock–water interactions, and reverse ion exchange processes. The IWQI, SAR, KI, and PS showed that the majority of the GW samples were categorized for irrigation purposes into no restriction (67.85%), excellent (100%), good (57.85%), and excellent to good (65.71%), respectively. Moreover, the majority of the selected samples were categorized as excellent to good and safe for irrigation according to the SSP and RSC. The performance of the simulation models was evaluated based on several prediction skills criteria, which revealed that the ANFIS model and SVM model were capable of simulating the IWQIs with reasonable accuracy for both training “determination coefficient (R2)” (R2 = 0.99 and 0.97) and testing (R2 = 0.97 and 0.76). The presented models’ promising accuracy illustrates their potential for use in IWQI prediction. The findings indicate the potential for ML methods of geographically dispersed hydrogeochemical data, such as ANFIS and SVM, to be used for assessing the GW quality for irrigation. The proposed methodological approach offers a useful tool for identifying the crucial hydrogeochemical components for GW evolution assessment and mitigation measures related to GW management in arid and semi-arid environments.
Monitoring and managing water quality parameters (WQPs) in water bodies (e.g., lakes) on a large scale using sampling-point techniques is tedious, laborious, and not highly representative. Hyperspectral and data-driven technology have provided a potentially valuable tool for the precise measurement of WQPs. Therefore, the objective of this work was to integrate WQPs, derived spectral reflectance indices (published spectral reflectance indices (PSRIs)), newly two-band spectral reflectance indices (NSRIs-2b) and newly three-band spectral indices (NSRIs-3b), and artificial neural networks (ANNs) for estimating WQPs in Lake Qaroun. Shipboard cruises were conducted to collect surface water samples at 16 different sites throughout Lake Qaroun throughout a two-year study (2018 and 2019). Different WQPs, such as total nitrogen (TN), ammonium (NH4+), orthophosphate (PO43−), and chemical oxygen demand (COD), were evaluated for aquatic use. The results showed that the highest determination coefficients were recorded with the NSRIs-3b, followed by the NSRIs-2b, and then followed by the PSRIs, which produced lower R2 with all tested WQPs. The majority of NSRIs-3bs demonstrated strong significant relationships with three WQPs (TN, NH4+, and PO43−) with (R2 = 0.70 to 0.77), and a moderate relationship with COD (R2 = 0.52 to 0.64). The SRIs integrated with ANNs would be an efficient tool for estimating the investigated four WQPs in both calibration and validation datasets with acceptable accuracy. For examples, the five features of the SRIs involved in this model are of great significance for predicting TN. Its outputs showed high R2 values of 0.92 and 0.84 for calibration and validation, respectively. The ANN-PO43−VI-17 was the highest accuracy model for predicting PO43− with R2 = 0.98 and 0.89 for calibration and validation, respectively. In conclusion, this research study demonstrated that NSRIs-3b, alongside a combined approach of ANNs models and SRIs, would be an effective tool for assessing WQPs of Lake Qaroun.
Standard methods are limited for monitoring and managing water quality indicators (WQIs) in real-time and on a large scale. Consequently, there is an urgent need to use reliable, practical, swift, and cost-effective monitoring tools that can be easily deployed and assist decision makers in assessing key indicators relevant to surface water quality in a comprehensive manner. Surface water samples were collected and evaluated for water quality at 16 distinct sites across the Qaroun Lake in 2018 and 2019. Different WQIs, including total dissolved solids (TDS), transparency, total suspended solids (TSS), chlorophyll-a (Chl-a), and total phosphorus (TP), were tested for aquatic utilization. An integrated approach comprising WQIs, geospatial techniques, hyperspectral reflectance indices (SRIs) (commonly used SRIs, two-band and three-band SRIs (Spectral index calculated from water spectral reflectance of two or three wavelengths)), and partial least square regression (PLSR) models were used to assess the water quality of Qaroun Lake. According to the findings, the water quality attributes are polluted to varying degrees. The majority of commonly used SRIs presented moderately relationship with four WQIs (transparency, TSS, Chl-a, and TP) (R2 = 0.45 to 0.64), while the majority of newly two-band SRIs (NSRIs-2b) indicated moderate to strong relationships with WQIs (R2 = 0.51 to 0.74), and the majority of newly three band SRIs (NSRIs-3b) presented strong relationships with WQIs (R2 = 0.67 to 0.81). Broadly, the highest coefficients of determination were noticed with the NSRIs-3b followed by the NSRIs-2b and then the commonly used SRIs. For example, the NSRIs-3b (NDSI648,712,696) had stronger relationships with transparency, TSS, and Chl-a with R2 = 0.77, 0.66, and 0.81, respectively, than other SRIs. In addition, the NSRIs-3b (NDSI620,610,622) showed the highest R2 of 0.73 with TSS. The NSRIs-3b coupling with PLSR predicted the WQIs with satisfactory accuracy in the calibration (reach up R2 = 0.85) and validation (reach up R2 = 0.81) datasets. The overall findings of this research study showed that deriving an optimized NSRIs-3b from spectrum region and combining it with PLSR model could be a practical tool for managing water quality of the Qaroun Lake by accurately, timely, and non-destructively monitoring the WQIs.
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