This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues.Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. The thermodynamics of structural phase transformations in thin films depends on the mechanical stress that can be released by plastic deformation. For thin films below a critical film thickness, plastic deformation is energetically unfavourable: thus, the system stays coherent and stress remains. For PdH c films less than 22 nm thick, a new situation emerges: while the interfaces between matrix and hydride precipitates remain coherent throughout the complete phase transition, misfit dislocations form between the hydride phase and the substrate.
In order to generate the bending motion operated by pressure change in hydrogen gas, soft uni-morph composites were prepared, in which composites dispersed with not only driving particles of LaNi 5 hydrogen storage alloy with Pd-Al 2 O 3 catalyst powders to get high responsiveness, were piled up on a simple polyurethane sheet. Since the highest values of irreversible bending strain at the first hydrogenation (" 1) under 0.3 MPa H 2 gas and the maximum irreversible bending strain during hydrogenation cycles (" m) were remarkably obtained at the 35 vol% of LaNi 5 powders dispersed in polyurethane composites, the bending strain of reversible motion was detected from the first to the 8th hydrogenation (" r 1 and " r 8) under 0.2 MPa H 2 gas. The bending strain of reversible motion of polyurethane composites sheet is more than 2000 ppm, which was approximately equal to that of silicone rubber composites and is extremely larger than that (300 ppm) of ABS resin composites. Responsiveness (d"=dt) of cyclic motion of elastic deformed mover composites, which were constructed with 35 vol%LaNi 5 dispersed powder and matrix of polyurethane or silicone rubber, were more than 10 times higher than that of ABS composite.
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