We study the interaction of thermal rubidium atoms with the guided mode of slot waveguides integrated in a vapor cell. Slot waveguides provide strong confinement of the light field in an area that overlaps with the atomic vapor. We investigate the transmission of the atomic cladding waveguides depending on the slot width, which determines the fraction of transmitted light power interacting with the atomic vapor. An elaborate simulation method has been developed to understand the behavior of the measured spectra. This model is based on individual trajectories of the atoms and includes both line shifts and decay rates due to atom-surface interactions that we have calculated for our specific geometries using the discrete dipole approximation. Furthermore, we investigate density-dependent effects on the line widths and line shifts of the rubidium atoms in the subwavelength interaction region of a slot waveguide.

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