In the process of creating sustainable heat and power production systems it is important to find alternative, renewable fuels that are carbon dioxide neutral. Preferably these fuels should be domestic, thus diminishing the need for transportation. One option could be to use existing residues from local agriculture and food production. Development of combustion methods suitable for such residues is presently being pursued by a number of companies. Because many biomass fuels have compositions that makes them inclined to cause ash sintering problems and emissions of acid gases, there may be a need for the use of additives to decrease such problems. The aim of this work was to examine the ash characteristics of some agricultural crops and residues and to find mixtures of fuels and additives that can form the basis for production of fuel pellets with minimal problems. The work is focused on biomass fuel pellets for small-scale grate-fired combustors. Three additives (limestone powder, kaolin, and sodium bicarbonate) were investigated regarding their effects on the ash melting behavior. The results show that calcium carbonate and kaolin both serve as good additives to prevent the formation of slag. The best antislagging effect was achieved when both additives were used. Sodium bicarbonate can be used as a sulfur binding additive, but this cannot be recommended since it increases the slag formation considerably. The conclusion is that combustion of agricultural crops and residues may be hampered by problems such as slag formation and ash fouling. However, through the use of suitable additives, the ash sintering characteristics can be improved significantly. This means that agricultural residues can be competitive fuels on the energy market in the future.

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