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The slow alteration of the surface of charred biomass (biochar) over time may contribute to an improved nutrient retention and thus fertility of tropical soils. Here, we investigated soils from temperate climates and investigated whether a technical steam activation of biochar could accelerate its positive effects on nutrient retention and uptake by plants relative to nonactivated biochar. To this aim, we performed microcosm experiments with sandy or silty soil, mixed with 2.0, 7.5 and 15.0 g/kg soil of fine (<2 mm) or coarse‐sized (2–10 mm) biochar from beech wood (Fagus sp.). After initial fertilizer (NPK), ashes and excess nutrients were leached with water, and the microcosms were planted for 142 days with Italian Ryegrass (Lolium multiflorum ssp. italicum). Thereafter, leachate, soil and plant samples were analysed for their nutrient contents. The results showed that biochar additions of ≤15 g/kg soil left elevated contents of available P and N in the surface soil but reduced their uptake into the plants. As a result, total biomass production was unchanged. Different particle size and application amounts influenced these findings only marginally. Nitrate leaching was enhanced in the sandy soil (+41% for nitrate, but reduced in the silty soil −17%) and P was immobilized. Hence, the fertility of the temperate soils under study was only marginally affected by pure biochar amendments. Steam activation, however, almost doubled the positive effects of biochars in all instances, thus being an interesting option for future biochar applications.

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Sulfur (S) deficiency of crops, which has been reported with increasing frequency over the past two decades on a worldwide scale, is a factor that reduces yield and affects the quality of harvested products. Especially in Western European countries, incidence of S deficiency has increasingly been reported in Brassicaceae. For this reason, more attention should be paid to the optimization of S‐fertilizer application, in order to cover plant S requirements whilst minimizing environmental impacts. In soils, S exists in inorganic and organic forms. While sulfate (SO$ _4^{2-} $), which is a direct S source for plants, contributes up to 5% of total soil S, generally more than 95% of soil S are organically bound. Organic S is divided into sulfate ester and carbon‐bonded S. Although not directly plant‐available, organically bound S may potentially contribute to the S supply of plants, especially in deficiency situations. Sulfur turnover involves both biochemical and biological mineralization. Biochemical mineralization, which is the release of SO$ _4^{2-} $ from the ester sulfate pool through enzymatic hydrolysis, is controlled by S supply, while the biological mineralization is driven by the microbial need for organic C to provide energy.

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We studied the long-term effect (about 45 years) of farmyard manure, sewage sludge and compost application in two increments on organic carbon (C org ), the amount (C mic ) and activity of the microbial biomass (soil respiration, dehydrogenase activity), total N content and N delivery of soils as compared to manuring with mineral fertilizers. The application of both increments of compost and the high sewage sludge application rate resulted in an increase in C org while soils treated with both compost application rates and the high farmyard manure application rate showed a significant increase in C mic . C mic /C org ranged between 1.7 and 3.3. Dehydrogenase activity and soil respiration were the greatest in the soil with the highest compost and farmyard manure application rates. Total soil N content was significantly higher in both compost treatments and in the treatment with the high sewage sludge application rate. This was accompanied by the highest N uptake of ryegrass.