This study aims to model road traffic noise levels and estimate the human exposure at the 25 districts in the metropolitan Seoul, Republic of Korea. The SoundPLAN® Version 7.1 software package was used to model noise levels and simulated road traffic noise maps were created. The people exposed to daytime/nighttime road traffic noise were also estimated. The proportions of the population exposed to road traffic noise in major cities in the EU were also estimated and compared. Eight (8) districts show the exceeded rate (percentage of the exposed population exceeding the daytime standard) of 20% or more, and eleven (11) districts show 10%-20% and six (6) districts show less than 10%, which indicates considerable variation among districts. Two districts (Nowon-gu and Yangcheon-gu) show the highest exposure rate during the daytime (35.2%). For nighttime noise levels, fourteen (14) districts show the exceeded rate (percentage of exposed population exceeding the nighttime standard) over 30%. The average percentages of the exposed population exceeding the daytime/nighttime standards in Seoul and the EU were 16.6%/34.8% and 13.0%/16.1%, respectively. The results show that road traffic noise reduction measures should urgently be taken for the nighttime traffic noise in Seoul. When the grid noise map and the 3-D façade noise map were compared, the 3-D façade noise map was more accurate in estimating exposed population in citywide noise mapping.
Described here is the oxygenative carbofunctionalization of terminal alkynes mediated by combined rhodium catalysis that enables regioselective quadruple formation of C−C, C−H, C−O, and C−heteroatom bonds. Mechanistic studies suggest that a disubstituted rhodium vinylidene complex is generated upon C−C bond formation at the terminal alkyne with tethered electrophiles such as alkyl halides, aldehydes, imines, and Michael acceptors. Subsequent intermolecular transfer oxygenation of the rhodium vinylidene with pyridine N-oxide generates a rhodium-complexed ketene intermediate that reacts with a variety of heteroatom nucleophiles to give rise to cyclic carboxylic acid derivatives.
Nowadays, the needs to revise the classification criteria for noise emission facilities have been suggested by the related industries. Because there existed many reasonable factors in the criteria regarding the noise emission facilities. And the noise emission facility classification criterion of the print machine changed from 50 HP to 100 HP in 2013. But the increasement of the noise emission facility classification criterion of the print machine can cause adverse effects like the bigger noise.So, in this paper, we measured the print machine's sound power level according to the changes of the print machine's power to assess the adverse effects. The measurement method applied with KS I ISO 9614-2(1996). The corelation between the sound power level and the power of print machines was analyzed by regression analysis. In this paper, we found that the sound power level of the print machines can increase about 1.3 dB in the condition of that the power of print machine increases from 50 HP to 100 HP. And we found that the sound power level of the print machines can increase about 1.0 dB for a increasement of 1,000 SPH(sheet per hour) of printing speed. The noise emission characteristics of print machine stuied in this paper will be useful to design the noise reduction plan in the future.
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