Low‐dimensional Ruddlesden‐Popper (LDRP) perovskites still suffer from inferior carrier transport properties. Here, we demonstrate that efficient exciton dissociation and charge transfer can be achieved in LDRP perovskite by introducing γ‐aminobutyric acid (GABA) as a spacer. The hydrogen bonding links adjacent spacing sheets in (GABA)2MA3Pb4I13 (MA=CH3NH3+), leading to the charges localized in the van der Waals gap, thereby constructing “charged‐bridge” for charge transfer through the spacing region. Additionally, the polarized GABA weakens dielectric confinement, decreasing the (GABA)2MA3Pb4I13 exciton binding energy as low as ≈73 meV. Benefiting from these merits, the resultant GABA‐based solar cell yields a champion power conversion efficiency (PCE) of 18.73 % with enhanced carrier transport properties. Furthermore, the unencapsulated device maintains 92.8 % of its initial PCE under continuous illumination after 1000 h and only lost 3 % of its initial PCE under 65 °C for 500 h.
Non-tuberculou Mycobacteria (NTM) is ubiquitous in the environment and is conditional pathogen. Due to NTM and Mycobacterium tuberculosis belong to the genus Mycobacterium, their pathogenic mechanisms and clinical manifestations are similar. Therefore, NTM can cause tuberculosis-like lesions and lead to misdiagnosis. Early diagnosis and treatment greatly improve prognosis. However, traditional pathogenic microorganism detection has limitations, and it is difficult to accurately identify strains in clinical practice. Here, we report a 65-year-old man with NTM who presented with recurrent fever and cough. Computed tomography of the chest revealed a lung infection. The previous improper diagnosis and treatment did not improve his condition. With the aid of metagenomic next-generation sequencing, the pathogen was identified as Mycobacterium avium complex. Subsequently, he received accurate treatment and made significant improvements in clinical and radiology.
Dynamic optimization of the quantum-well (QW) width distribution in quasi-2D halide perovskite thin films is an effective approach for tuning the properties of photoelectric devices. Here, that the QWs width distribution in quasi-2D perovskite films can be controlled only by using hydroiodic acid (HI) as an additive is demonstrated. A uniform distribution of the colloidal particle size in the quasi-2D perovskite precursor solution is achieved through the formation of soluble iodoplumbate coordination complexes, PbI 3 − from the reaction of HI with PbI 2 , resulting in an improved phase purity in the final film. Density functional theory calculations indicate that the ideal n value quasi-2D perovskite reaction pathway through the PbI 3 − complex has a lower enthalpy of formation than the random nucleation pathway without the HI additive. Benefiting from this merit, a high-quality quasi-2D perovskite film with optimized phase purity delivered a balanced carrier diffusion length and improved carrier mobility. The resultant photodetectors exhibited a light on/off ratio of 50 000, a responsivity of 0.96 A W −1 , and a detectivity of 5.7 × 10 12 Jones at 532 nm. In addition, the state-of-the-art device maintained more than 80% of its initial photocurrent after 720 h of storage at 30% relative humidity.
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