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Agriculture has significantly aided in meeting the food needs of growing population. In addition, it has boosted economic development in irrigated regions. In this study, an assessment of the groundwater (GW) quality for agricultural land was carried out in El Kharga Oasis, Western Desert of Egypt. Several irrigation water quality indices (IWQIs) and geographic information systems (GIS) were used for the modeling development. Two machine learning (ML) models (i.e., adaptive neuro-fuzzy inference system (ANFIS) and support vector machine (SVM)) were developed for the prediction of eight IWQIs, including the irrigation water quality index (IWQI), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), potential salinity (PS), residual sodium carbonate index (RSC), and Kelley index (KI). The physicochemical parameters included T°, pH, EC, TDS, K+, Na+, Mg2+, Ca2+, Cl−, SO42−, HCO3−, CO32−, and NO3−, and they were measured in 140 GW wells. The hydrochemical facies of the GW resources were of Ca-Mg-SO4, mixed Ca-Mg-Cl-SO4, Na-Cl, Ca-Mg-HCO3, and mixed Na-Ca-HCO3 types, which revealed silicate weathering, dissolution of gypsum/calcite/dolomite/ halite, rock–water interactions, and reverse ion exchange processes. The IWQI, SAR, KI, and PS showed that the majority of the GW samples were categorized for irrigation purposes into no restriction (67.85%), excellent (100%), good (57.85%), and excellent to good (65.71%), respectively. Moreover, the majority of the selected samples were categorized as excellent to good and safe for irrigation according to the SSP and RSC. The performance of the simulation models was evaluated based on several prediction skills criteria, which revealed that the ANFIS model and SVM model were capable of simulating the IWQIs with reasonable accuracy for both training “determination coefficient (R2)” (R2 = 0.99 and 0.97) and testing (R2 = 0.97 and 0.76). The presented models’ promising accuracy illustrates their potential for use in IWQI prediction. The findings indicate the potential for ML methods of geographically dispersed hydrogeochemical data, such as ANFIS and SVM, to be used for assessing the GW quality for irrigation. The proposed methodological approach offers a useful tool for identifying the crucial hydrogeochemical components for GW evolution assessment and mitigation measures related to GW management in arid and semi-arid environments.

Spectral reflectance indices (SRIs) often show inconsistency in estimating plant traits across different growth conditions; thus, it is still necessary to develop further optimized SRIs to guarantee the performance of SRIs as a simple and rapid approach to accurately estimate plant traits. The primary goal of this study was to develop optimized two- and three-band vegetation- and water-SRIs and to apply different multivariate regression models based on these SRIs for accurately estimating the relative water content (RWC), gravimetric water content (GWCF), and grain yield (GY) of two wheat cultivars evaluated under three irrigation regimes (100%, 75%, and 50% of crop evapotranspiration (ETc)) for two seasons. Results showed that the three plant traits and all SRIs showed significant differences (p < 0.05) between the three irrigation treatments for each wheat cultivar. The three-band water-SRIs (NWIs-3b) showed the best performance in estimating the three plant traits for both cultivars (R2 > 0.80), and RWC and GWCF under 75% ETc (R2 ≥ 0.65). Four out of six three-band vegetation-SRIs (NDVIs-3b) performed better than any other SRIs for estimating GY under 100% ETc and 50% ETC, and RWC under 100% ETc (R2 ≥ 0.60). All types of SRIs demonstrated excellent performance in estimating the three plant traits (R2 ≥ 0.70) when the data of all growth conditions were combined and analyzed together. The NWIs-3b coupled with Random Forest models predicted the three plant traits with satisfactory accuracy for the calibration (R2 ≥ 0.96) and validation (R2 ≥ 0.93) datasets. The overall results of this study elucidate that extracting an optimized NWIs-3b from the full spectrum data and combined with an appropriate regression technique could be a practical approach for managing deficit irrigation regimes of crops through accurately, timely, and non-destructively monitoring the water status and final potential yield.

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