Slaughterhouse waste is considered to be an emerging issue because of its disposal cost. As an alternative, it would be a great prospect for the bioeconomy society to explore new usages of these leftover materials. As per food safety rules mentioned by EU legislation, all bone waste generated by slaughterhouses ought to be disposed of by rendering. The huge quantity of worldwide bone waste generation (130 billion kilograms per annum) is an environmental burden if not properly managed. The waste animal bones can be efficiently employed as a heterogeneous catalyst to produce biodiesel. This mini review summarized the recent literature reported for biodiesel generation using waste animal bones derived heterogeneous catalyst. It discusses the sources of bone waste, catalyst preparation methods, particularly calcination and its effects, and important characteristics of bones derived catalyst. It suggests that catalysts extracted from waste animal bones have suitable catalytic activity in transesterification of different oil sources to generate a good quality biodiesel.
Municipal solid waste (MSW) contains plastic waste that can be used as a sustainable green substitute to reduce oil footprints, CO2 emissions, and environmental pollution. This study aims to recycle plastic waste by manufacturing wood-plastic composites and to improve its mechanical properties by using additives, coupling agents, and lubricants. These composites are prepared by mixing 40–70% of wood flour with 20–25% of a polymer matrix. Wood was degraded at 220 °C, and then the composites were processed at 50 °C. The manufacturing process carried out in the study involved wood waste meshing, drying, shredding, drying, trimming, filling, blending, compounding, and extrusion moulding. The compounding of composites was accomplished in twin-screw extruders. Once the mixture was uniformly mixed, its final shape was given by a two-step extrusion moulding. Previously, researchers aimed at enhancing the mechanical properties of the composites, but our research focus was to improve their durability for different industrial applications. The results suggest that the impact strength is 17 MPa with 50% of wood powder ratio while the maximum value for the tensile strength is 32.5 MPa. About 50% of an increase in wood powder resulted in 8.1% bending strength increase from 26.1 to 32.8 MPa. Reducing the plastic matrix and the wood-particles water swelling ratio resulted in better mechanical properties. The wood species also affected the mechanical properties with their excellent dimensional stability and less variability. A high proportion of wood fibre tends to increase its steady-state torque and viscosity. The mechanical properties against different wood-flour proportions indicate that composite materials exhibit superior water swelling behaviour and extrusion quality.
The demand for alternative fuels has risen in recent years due to the economic and environmental consequences of conventional fuels. In addition to engine characteristics, i.e., performance, combustion, and emission the lubricity of the considered fuel is an important parameter for its selection. This experimental study shows the tribological performance of the tire pyrolysis oil by using the four-ball tester. Waste tire pyrolysis oil was purified by using the distillation process. The experiment was conducted over 300 s at 40, 50, 63, and 80 kg load, 1800 rpm constant speed, and 27 °C temperature of all fuels on the ASTM D2266 standard. The tribological performance of the tire pyrolysis oil was compared with the BT10 (biodiesel 90%–tire pyrolysis oil 10%) and BT20 (biodiesel 80%–tire pyrolysis oil 20%) and biodiesel. The optical microscope is used to measure the wear scar diameter and then it is examined through a scanning electron microscope. In terms of greater load-carrying capacity, tire pyrolysis oil shows better anti-wear behaviour compared to biodiesel fuel. The wear scar diameter of BT10, BT20, and tire pyrolysis oil was 23.99%, 8.37%, and 32.62%, respectively, lower than the biodiesel fuel at 80 kg load. The SEM micrographs revealed that tire pyrolysis oil and BT10 displayed lower wear as compared to counterparts. Finally, it is concluded that BT10 is the most suitable fuel in terms of tribological performance.
Energy is essential for the nature of life and the development of countries. The main demand for the 21st century is to fulfill growing energy needs. Pakistan, through the use of fossil fuels, meets energy demands. There is pressure on the economy of the country due to the massive reliance on fossil fuels, and this tendency is influenced by various environmental impacts. To overcome the burden on fossil fuels, more attention has been drawn to provide fossil fuel substitution. Tire pyrolysis is among the effective substitutes of the fuel technology that generates useful products of liquid oil, char, and pyro gas. This research focuses on the environmental, social, and economic viability of tire pyrolysis oil in Pakistan. This study estimates the production and potential of tire pyrolysis oil (TPO) in Pakistan. Based on the calculations, the potential of tire pyrolysis oil production in Pakistan from 2015–2019 is 468,081 to 548,406 tons. The potential production of TPO in 2018–2019 was ~8.30% of the total import (6.6 million tons) of crude oil. Therefore, tire pyrolysis oil is considered an alternative fuel representing an economic and environmentally viability solution for Pakistan.
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