Reaction pathways of biochemical processes are influenced by the dissipative electrostatic interaction of the reagents with solvent water molecules. The simulation of these interactions requires a parametrization of the permanent and induced dipole moments. However, the underlying molecular polarizability of water and its dependence on ions are partially unknown. Here, we apply intense terahertz pulses to liquid water, whose oscillations match the timescale of orientational relaxation. Using a combination of terahertz pump / optical probe experiments, molecular dynamics simulations, and a Langevin dynamics model, we demonstrate a transient orientation of their dipole moments, not possible by optical excitation. The resulting birefringence reveals that the polarizability of water is lower along its dipole moment than the average value perpendicular to it. This anisotropy, also observed in heavy water and alcohols, increases with the concentration of sodium iodide dissolved in water. Our results enable a more accurate parametrization and a benchmarking of existing and future water models.
This paper aims to investigate the energy saving and carbon reduction performance of cross-laminated timber residential buildings in the severe cold region of China through a computational simulation approach. The authors selected Harbin as the simulation environment, designed reference residential buildings with different storeys which were constructed using reinforced concrete (RC) and cross-laminated timber (CLT) systems, then simulated the energy performance using the commercial software IES TM and finally made comparisions between the RC and CLT buildings. The results show that the estimated energy consumption and carbon emissions for CLT buildings are 9.9% and 13.2% lower than those of RC buildings in view of life-cycle assessment. This indicates that the CLT construction system has good potential for energy saving when compared to RC in the severe cold region of China. The energy efficiency of residential buildings is closely related to the height for both RC and CLT buildings. In spite of the higher cost of materials for high-rise buildings, both RC and CLT tall residential buildings have better energy efficiency than low-rise and mid-rise buildings in the severe cold region of China.
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