A new microporous MIL-100(Fe)/Ti3C2 MXene composite was constructed as a non-noble
metal-based Schottky junction photocatalyst with improved nitrogen
fixation ability. Ti3C2 MXene nanosheets exhibited
excellent metal conductivity and were employed as two-dimensional
support to optimize the composite’s energy band structure.
MIL-100(Fe) with a large specific surface area was used as an adsorbent
and a photocatalytic oxidation center. The MIL-100(Fe)/Ti3C2 MXene composite not only exhibited higher thermal stability
but also showed significantly increased nitrogen fixation activity
under visible light. The NO conversion rate of the composite catalyst
was about four and three times higher than that of the pure Ti3C2 MXene and the pure MIL-100(Fe) samples, respectively.
Although adsorption plays an important role in the nitrogen fixation
process, the synergistic effects of the Schottky junctions are the
main cause of the enhanced photocatalytic activity. The built-in electric
field can be generated to form charge-transfer channels, which help
to achieve a desirable photocatalytic activity.
In
this work, a novel heterojunction catalyst was constructed by
introducing Ti3C2 MXene quantum dots (QDs) into
SiC. The Ti3C2 MXene QDs/SiC composite showed
74.6% efficiency in NO pollutant removal under visible light irradiation,
which is 3.1 and 3.7 times higher than those of the bare Ti3C2 MXene quantum dots and SiC, respectively. The Ti3C2 MXene quantum dots existing in SiC can function
as a channel for electron and hole transfer. The enhanced visible
light absorption, increased superoxide radical, and strong oxidization
ability endow the Ti3C2 MXene QDs/SiC composite
with a superior photocatalytic performance for NOx removal. The increased
superoxide radical formation and enhanced oxidization ability of Ti3C2 MXene QDs/SiC were demonstrated by theoretical
calculations. The robust stability in both photocatalytic performance
and crystal structures was revealed in the Ti3C2 MXene QDs/SiC composite using the cycling test, transient photocurrent
response, XRD, and TG.
In this work, the g-C3N4/V2C MXene composite catalyst was prepared by solvothermal method, and its denitration performance under synergistic plasma (NTP) was investigated. The results showed that when the mass ratio of V2C is 3%, the denitration performance of V-CN-3-NTP is as high as 83.3%, which is 1.2 and 2.1 times that of the V2C-NTP and g-C3N4-NTP systems alone. The apparent morphology, phase structure, and catalytic mechanism of the catalyst were studied by SEM, TEM, XRD, FTIR, XPS, etc. The results showed that g-C3N4 grows well on V2C mxene. V2C is not only an electron acceptor but also an active site for NO adsorption. The electrons and holes generated by V2C could be effectively separated by the high-voltage electric field, which improves the denitration performance and shows a good synergistic effect.
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