h i g h l i g h t s Simultaneous As(III) and F removal is achieved by using granular TiO 2-La composite. LaCO 3 OH showing orientated growth on TiO 2 {1 0 0} facet with matched lattice fringes. Molecular-level coadsorption mechanism is investigated by EXAFS and DFT calculation. The importance of crystal facet in material synthesis and adsorption is highlighted.
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