Ceria supported on platinum substrate is one of the most extensively studied inverse model catalysts. Unraveling the atomic structure of the ceria film is of great importance in helping understand the performance of ceria-involving heterogeneous catalysis. In this study, scanning tunneling microscopy (STM), apparent local work function (LWF) measurement, and density functional theory (DFT) calculations are employed to explore the atomic structures of the ceria islands and their electronic interaction with the Pt(111) substrate. High-resolution STM images and DFT calculations have unraveled the atomic structures of the prepared 3:4 coincidence cells and the island step edges on Pt(111). In specific, the structural difference between the two triangular half units is unprecedentedly achieved on the atomic level. The charge transfer between the ceria island and Pt(111) dependent on the interfacial structure has also been uncovered by apparent LWF measurements.
A heterogeneous catalytic process involves many surface elementary steps that affect the overall catalytic performance in one way or another. In general, a high-performance heterogeneous catalyst should meet the main criteria: excellent catalytic activity and high selectivity toward target products. Using surface science techniques, the two-sidedness of the surface reaction mediations can be explored, from the perspectives of the surface and the molecule manipulations. The surface manipulation refers to a reaction that is mediated by composition and structure of the substrate as well as surface species, while the molecular manipulation relates to a reaction that is mediated by the reacting molecule via the precursor selection, environmental control, or external excitation. The best catalytic system should consist of the most efficient catalyst and the best suitable reacting molecule, in addition to its economic benefit and environmental amity. Recent research progress in surface reaction mediation is outlined, and its two-sidedness is governed by the Arrhenius equation. This should shed new light on the connection between basic theory and surface reaction mediation strategies. To conclude, challenges and possible opportunities are elaborated for efficient surface reaction mediations.
Ceria has been widely applied as a support in heterogeneous catalysis due to its unique capability to store and release oxygen. As a typical inverse model catalyst, a ceria/Pt(111) system has attracted much attention due to its strong metal-oxide interaction. The structural and electronic properties of the ceria/Pt(111) system can be effectively modified by the introduction of alien K and Rh atoms. Here, the K- and Rh-modified ceria/Pt(111) inverse model catalysts have been investigated with high resolution scanning tunneling microscopy and apparent local work function measurement. The experimental results indicate that the K atoms prefer to occupy the top sites of the stoichiometric ceria, while the Rh atoms are prone to stay at the electron-rich ceria island edges. The K and Rh atoms act as an electron donor and acceptor on ceria/Pt(111), respectively. Such a study on the modification of the ceria-based catalysts should help understand strong metal-oxide interaction in heterogeneous catalysis at the atomic level.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.