All‐solid‐state lithium metal batteries (ASSLMBs) are becoming the crucial energy‐storage candidate in achieving both theoretical capacity and safety guarantee. However, the inherent defects of solid electrolytes (SEs) (low ionic conductivity, lack of mechanical properties, weak antioxidant capacity, etc.) and the existence of interfacial issues between electrodes (cathode/electrolyte interface and anode/electrolyte interface) hinder further practical application. To overcome these problems, many approaches have been developed, such as composite solid electrolytes, interfacial coatings, electrolyte additives, etc. Among them, fluorides and its derivatives with good chemical stability are generally believed as one of the significant materials for stabilizing ASSLMBs. In this article, the progress of fluorinated strategies in ASSLMBs is summarized from the aspects of fluorinated SEs and fluorinated interfaces. Meanwhile, the enhanced mechanisms of fluorinated strategies are emphasized from the microscopic view of the nanostructures evolution based on the discussion of emerging analysis technologies such as cryogenic transmission electron microscopy. The progress of future fluorinated strategies is prospected, and this review may thus instruct the rational design of high performance ASSLMBs.
The magnetic circuit of existing linear force motors does not consider the issue of energy utilization of permanent magnets, and the structure is complicated. To achieve high energy utilization and simplify the structure, this paper presents a novel magnetic circuit topology for the linear force motors of electro-hydraulic servo-proportional valves. In order to rapidly and accurately calculate the static characteristics of the force motor, an analytical model is established by using the equivalent magnetic circuit method. The model comprehensively considers the magnetic leakage effect, edge effect, and permeability nonlinearity. A prototype of the force motor is designed and manufactured, and a special experimental platform is built. The prototype force motor has a linear force-displacement characteristic and the output force increases with the increase of the excitation currents, which can reach about 41N at 2A. This indicates that it is suitable as an electro-mechanical converter for electro-hydraulic servo-proportional valves. Moreover, the analytical model is used to perform parameter optimization and calculate the magnetic flux density in the working air gap and the force-displacement characteristics under different excitation currents. The results are in good agreement with the electromagnetic field finite element simulation and experimental results. They indicate that the analytical model can rapidly and accurately predict the static characteristics of the force motor. The research work provides good reference means for the design of magnetic circuit topology with consideration of the high energy utilization of permanent magnets, and also the accurate analytical modeling of valve electro-mechanical converters.
Although a two-dimensional (2D) valve has excellent performance, the processing of its spiral groove has a high cost and is time-consuming. This paper proposes a novel torque motor based on an annulus air gap (TMAAG) to replace the negative feedback function of the spiral groove to reduce the machining difficulty. In order to study the torque change law of the TMAAG, the air gap permeance was analyzed, and then a qualitative analytical model was established. Orthogonal tests were carried out to initially select the crucial parameters, which were further optimized through a back propagation (BP) neural network and genetic algorithm. The prototype of TMAAG was machined, and a special experimental platform was built, and experiment results are similar to the simulation values, which verifies the accuracy of the air gap analysis and qualitative model. For torque-angle characteristics, the output torque increases with both current and rotation angle and reaches about 0.754 N·m with 2 A and 1.5°. While for torque-displacement characteristics, due to the negative feedback mechanism, the output torque decreases with increasing armature displacement, which is about 0.084 N·m with 2 A and 1 mm. The research validates the unique negative feedback mechanism of the TMAAG and indicates that it can be potentially used as an electro-mechanical converter of a 2D valve.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.