A novel soluble Azo-POP (named Azo-POP-7) was reported for the highly efficient organic-aqueous biphasic reduction reaction on 4-nitrophenol with good recyclability (12 cycles).
Irreversible tautomerization could lead to fascinating functional porous organic polymers such as TKH-POPs comprising tris(β-keto-hydrazo)-cyclohexane subunit.
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