:A good mechanical model of magnetorheological damper (MRD) is essential to predict the shock isolation performance of MRD in numerical simulation. But at present, the mechanical models of MRD were all derived from the experiment subjected to harmonic vibration loads. In this paper, a commercial MRD (type RD-1005-3) manufactured by Lord Corporation was studied experimentally in order to investigate its isolation performance under the impact loads. A new mechanical model of MRD was proposed according to the data obtained by impact test. A good agreement between the numerical results and test data was observed, which showed that the model was good to simulate the dynamic properties of MRD under impact loads. It is also demonstrated that MRD can improve the acceleration and displacement response of the structure obviously under impact loads.
The tuned liquid column damper (TLCD), a passive damping device consisting of a large U-tube with oscillating liquid, has been shown to be effective at mitigating structural responses under natural hazards. Aside from their bandwidth-limited mitigation capabilities, a key limitation of TLCDs is in their large geometries that occupy large space often at prime locations. A solution is to implement multicolumned versions, termed tuned liquid multiple columns dampers (TLMCDs), which have the potential to be tuned to multiple frequencies and occupy less space by leveraging the multiple columns to allow fluid movement. However, mathematical models characterizing their dynamic behavior must be developed enabling proper tuning and sizing in the design process. In this paper, a new analytical model characterizing a TLMCD as a multiple degrees-of-freedom coupled nonlinear system is presented. The frequencies of free vibration and vibration modes of a TLMCD are identified in closed-form formulations. Results are validated using computational fluid dynamics simulations, and show that the analytical model can predict the damper's liquid surface movements as well as its capability to reduce structural vibration when the structure is subjected to harmonic excitations. A parametric study is conducted to investigate the effect of head loss coefficients, column spacing, cross-section area ratios, and column numbers on mitigating structural response. It is found that, while TLMCDs are less effective than traditional TLCDs under an equal liquid mass, they can provide enhanced performance under geometric restrictions.
A new energetic copper complex of dinitroacetonitrile (DNANT), [Cu(NH3)4](DNANT)2, was first synthesized through an unexpected reaction. The thermal decomposition of [Cu(NH3)4](DNANT)2 was studied with DSC and TG/DTG methods. The gas products were analyzed through a TG-FTIR-MS method. The nonisothermal kinetic equation of the exothermic process is dα/dT = 10(10.92)/β4(1 - α)[-ln(1 - α)](3/4) exp(-1.298 × 10(5)/RT). The self-accelerating decomposition temperature and critical temperature of thermal explosion are 217.9 and 221.0 °C. The specific heat capacity of [Cu(NH3)4](DNANT)2 was determined with a micro-DSC method, and the molar heat capacity is 512.6 J mol(-1) K(-1) at 25 °C. Adiabatic time-to-explosion of Cu(NH3)4(DNANT)2 was also calculated to be about 137 s.
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