To improve the energy density of supercapacitors, a new type of electrode material with high electrochemical activity and favorable morphology is extremely desired.
A novel electrode material based on graphene oxide (GO)-polypyrrole (PPy) composites was synthesized by in situ chemical oxidation polymerization. Palladium nanoparticles (NPs) with a diameter of 4.0 nm were loaded on the reduced graphene oxide(RGO)-PPy composites by a microwave-assisted polyol process. Microstructure analysis showed that a layer of coated PPy film with monodisperse Pd NPs is present on the RGO surface. The Pd/RGO-PPy catalysts exhibit excellent catalytic activity and stability for formic acid electro-oxidation when the weight feed ratio of GO to pyrrole monomer is 2:1. The superior performance of Pd/RGO-PPy catalysts may arise from utilization of heterogeneous nucleation sites for NPs and the greatly increased electronic conductivity of the supports.
Developing flexible and lightweight energy storage systems for miniaturized electronic equipment and high volumetric performance is arousing increasing interest.
The serious limitations of MnO2 are poor electrical conductivity and low utilization rate of electrochemical active area. These problems have seriously limited the application of MnO2 aqueous zinc‐ion batteries (AZIBs). Herein, preparing MnO2 uniformly loaded on carbon nanotubes with good electrical conductivity can greatly improve the poor electrical conductivity of MnO2. Moreover, by introducing oxygen vacancy, the surface capacitance, the reaction kinetics, and the electrochemical performance of MnO2 is increased. The specific capacity of the Vo‐MnO2/CNT material is 314 mAh g−1, at 0.2 A g−1, and capacity retention of 81% is achieved after 1000 cycles. In particular, the prepared device presents a distinct energy density of 416.2 Wh kg−1. As a result, the capacity as well as the cycle stability is effectively improved compared with the original MnO2.
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