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A novel squaraine-based chemosensor SQ-1 has been synthesized, and its sensing behavior toward various metal ions was investigated by UV-vis and fluorescence spectroscopies. In AcOH-H(2)O (40:60, v/v) solution, Hg(2+) ions coordinate with SQ-1 causing a deaggregation which induces a visual color and absorption spectral changes as well as strong fluorescence. In contrast, the addition of other metals (e.g., Pb(2+), Cd(2+), Cu(2+), Zn(2+), Al(3+), Ni(2+), Co(2+), Fe(3+), Ca(2+), K(+), Mg(2+), Na(+), and Ag(+)) does not induce these changes at all. Thus SQ-1 is a specific Hg(2+) sensing agent due to the inducing deaggregation of the dye molecule by Hg(2+).

The petroleum ether-ether (1 : 1) extract of Atractylodis macrocephalae was screened by cell membrane chromatography (CMC) and subsequently separated by column chromatography (CC) and high performance liquid chromatography (HPLC). Five components were isolated and identified as atractylenolide III 1, atractylenolide I 2, 14-acetoxy-12-senecioyloxytetradeca-2E,8E,10E-trien-4,6-diyn-1-ol 3, 14-acetoxy-12-alpha-methylbutyl-2E,8E,10E-trien-4,6-diyn-1-ol 4 and 14-acetoxy-12-beta-methylbutyl-2E,8E,10E-trien-4,6-diyn-1-ol 5 by routine spectrometric methods. The data of 5 and (13)C-NMR data of 3 and 4 were reported for the first time. Further in vivo experiments showed that the five components exhibited significant inhibiting effects both on the ear edema induced by xylene and on the peritoneal capillary permeability induced by acetic acid in mice.

Adopting the scaling functions of B-spline wavelet on the interval (BSWI) as trial functions, a new finite element method (FEM) of BSWI is presented. Instead of traditional polynomial interpolation, scaling functions at the certain scale have been adopted to form the shape functions and construct wavelet-based elements. Unlike the process of wavelets added directly in the other wavelet numerical methods, the element displacement field represented by the coefficients of wavelets expansions is transformed from wavelet space to physical space via the corresponding transformation matrix. The transformation matrix is the key to construct wavelet-based elements freely as long as we can ensure its non-singularity. Then, classes of C 0 and C 1 type elements are constructed. And the lifting scheme of BSWI elements is also discussed. The numerical examples indicate that the BSWI elements have higher efficiency and precision than traditional finite element method in solving 1D structural problems especially for geometric nonlinear, variable cross-section and loading cases.

Comparison and comparability lie at the heart of any comparative social science. Still, precise comparison is virtually impossible without using similar methods and similar data. In recent decades, social demographers, historians, and economic historians have compiled and made available a large number of micro-level data sets of historical populations for North America and Europe. Studies using these data have already made important contributions to many academic disciplines. In a similar spirit, we introduce five new microlevel historical panel data sets from East Asia, including the China Multi-Generational Panel Dataset–Liaoning (CMGPD-LN) 1749–1909, the China Multi-Generational Panel Dataset– Shuangcheng (CMGPD-SC) 1866–1913, the Japanese Ninbetsu-Aratame-Cho Population Register Database–Shimomoriya and Niita (NAC-SN) 1716–1870, the Korea Multi-Generational Panel Dataset–Tansung (KMGPD-TS) 1678–1888, and the Colonial Taiwan Household Registration Database (CTHRD) 1906–1945. These data sets in total contain more than 3.7 million linked observations of 610,000 individuals and are the first such Asian data to be made available online or by application. We discuss the key features and historical institutions that originally collected these data; the subsequent processes by which the data were reconstructed into individual-level panels; their particular data limitations and strengths; and their potential for comparative social scientific research.

Among the vibration-based fault diagnosis methods for rolling element bearing, the shock pulse method (SPM) combined with the demodulation method is a useful quantitative technique for estimating bearing running state. However, direct demodulation often misestimates the shock value of characteristic defect frequency. To overcome this disadvantage, the vibration signal should be decomposed before demodulation. Empirical mode decomposition (EMD) can be an alternative for preprocess bearing fault signals. However, the trouble with this method's application is that it is time-consuming. Therefore, a novel method that can improve the sifting process's efficiency is proposed, in which only one time of cubic spline fitting is required in each sifting process. As a consequence, the time for EMD analysis can be evidently shortened and the decomposition results simultaneously maintained at a high precision. Simulations and experiments verify that the improved EMD method, combined with SPM and demodulation analysis, is efficient and accurate and can be effectively applied in engineering practice.

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Human child survival depends on adult investment, typically from parents. However, in spite of recent research advances on kin influence and birth order effects on human infant and child mortality, studies that directly examine the interaction of kin context and birth order on sibling differences in child mortality are still rare. Our study supplements this literature with new findings from large-scale individual-level panel data for three East Asian historical populations from northeast China (1789–1909), northeast Japan (1716–1870), and north Taiwan (1906–1945), where preference for sons and first-borns is common. We examine and compare male child mortality risks by presence/absence of co-resident parents, grandparents, and other kin, as well as their interaction effects with birth order. We apply discrete-time event-history analysis on over 172,000 observations of 69,125 boys aged 1–9 years old. We find that in all three populations, while the presence of parents is important for child survival, it is more beneficial to first/early-borns than to later-borns. Effects of other co-resident kin are however null or inconsistent between populations. Our findings underscore the importance of birth order in understanding how differential parental investment may produce child survival differentials between siblings.