The rate-determining reaction step is associated with the C–H bond cleavage of –CH2 group of the first HMF molecule oxidized by [V(O)2(DMA)2]+ species, while counteranion Cl− exhibits catalytically promotive effect.
In sorbitol solution with Ga(OTf)3 compound, the coordination of sorbitol (SBT) to [Ga(OTf)n]3–n (n = 0 ~ 3) has been investigated, using both ESI-MS spectra and the density functional theory...
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