Archean ultramafic-mafic complexes have been the focus of important and often contentious geological and geodynamic interpretations. However, their age relative to the other components of Archean cratons are often poorly-constrained, introducing significant ambiguity when interpreting their origin and geodynamic significance. The Lewisian Gneiss Complex (LGC) of the northwest Scottish mainland -a high-grade, tonalite-trondhjemite-granodiorite (TTG) terrane that forms part of the North Atlantic Craton (NAC) -contains a number of ultramafic-mafic complexes whose origin and geodynamic significance have remained enigmatic since they were first described. Previous studies have interpreted these complexes as representing a wide-range of geological environments, from oceanic crust, to the sagducted remnants of Archean greenstone belts. These interpretations, which are often critically dependent upon the ages of the complexes relative to the surrounding rocks, have disparate implications for Archean geodynamic regimes (in the NAC and globally). Most previous authors have inferred that the ultramafic-mafic complexes of the LGC pre-date the TTG magmas. This fundamental age relationship is re-evaluated in this investigation through re-mapping of the Geodh' nan Sgadan Complex (where tonalitic gneiss reportedly cross-cuts mafic rocks) and new mapping of the 7 km 2 Ben Strome Complex (the largest ultramafic-mafic complex in the LGC), alongside detailed petrography and spinel mineral chemistry. This new study reveals that, despite their close proximity in the LGC (12 km), the Ben Strome and Geodh' nan Sgadan Complexes are petrogenetically unrelated, indicating that the LGC (and thus NAC) records multiple temporally and/or petrogenetically distinct phases of ultramafic-mafic Archean magmatism that has been masked by subsequent high-grade metamorphism. Moreover, field observations and spinel mineral chemistry demonstrate that the Ben Strome Complex represents a layered intrusion that was emplaced into a TTG-dominated crust. Further to representing a significant re-evaluation of theLGC's magmatic evolution, these findings have important implications for the methodologies utilised in deciphering the origin of Archean ultramafic-mafic complexes globally, where material suitable for dating is often unavailable and field relationships are commonly ambiguous.

The Aurora Project is a Cu-Ni-PGE magmatic sulphide deposit in the northern limb of the Bushveld Complex of South Africa. Since 1992 mining in the northern limb has focussed on the Platreef deposit, located along the margin of the complex. Aurora has previously been suggested to represent a far-northern facies of the Platreef located along the basal margin of the complex and this study provides new data with which to test this assertion. In contrast to the Platreef, the base metal sulphide mineralisation at Aurora is both Cu-rich (Ni/Cu <1) and Au-rich. The sulphides are hosted predominantly in leucocratic rocks (gabbronorites and leucogabbronorites) with low Cr/MgO (<30) where pigeonite and orthopyroxene co-exist as low-Ca pyroxenes without cumulus magnetite.This mineral association is found in the Upper Main Zone and the Aurora mineral chemistry is consistent with this stratigraphic interval. Pigeonite gabbronorites above the Aurora mineralisation have high Cu/Pd ratios (>50000) reflecting the preferential removal of Pd over Cu in the sulphides below. Similarly high Cu/Pd ratios characterise the Upper Main Zone in the northern limb above the pigeonite + orthopyroxene interval and suggest that Aurora-style sulphide mineralisation may be developed here as well. The same mineralogy and geochemical features also appear to be present in the T Zone of the Waterberg PGE deposit, located under younger cover rocks to the north of Aurora.If these links are proved they indicate the potential for a previously unsuspected zone of Cu-Ni-PGE mineralisation extending for over 40km along strike through the Upper Main Zone of the northern Bushveld.

Bulk rock geochemistry and major-and trace-element compositions of clinopyroxene have been determined for three suites of peridotitic mantle xenoliths from the North Atlantic Craton (NAC) in northern Scotland, to establish the magmatic and metasomatic history of subcontinental lithospheric mantle (SCLM) below this region. Spinel lherzolites from the southernmost locality (Streap Com'laidh) have non-NAC mantle compositions, while the two northern xenolith suites (Loch Roag and Rinibar) are derived from the thinned NAC marginal keel. Clinopyroxene compositions have characteristic trace-element signatures which show both 'primary' and 'metasomatic' origins. We use Zr and Hf abundances to identify ancient cryptic refertilization in 'primary' clinopyroxenes. We suggest that Loch Roag and Rinibar peridotite xenoliths represent an ancient ArchaeanPalaeoproterozoic SCLM with original depleted cratonic signatures which were overprinted by metasomatism around the time of intrusion of the Scourie Dyke Swarm (~2.4 Ga). This SCLM keel was preserved during Caledonian orogenesis, although some addition of material and/or metasomatism probably also occurred, as recorded by Rinibar xenoliths. Rinibar and Streap xenoliths were entrained in Permo-Carboniferous magmas and thus were isolated from the SCLM~200 Ma before Loch Roag xenoliths (in an Eocene dyke). Crucially, despite their geographical location, lithospheric mantle peridotite samples from Loch Roag show no evidence of recent melting or refertilization during the Palaeogene opening of the Atlantic.

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Concern about security of supply of critical elements used in new technologies, such as the Rare Earth Elements (REE), means that it is increasingly important to understand the processes by which they are enriched in crustal settings. High REE contents are found in syenitedominated alkaline complexes intruded along the Moine Thrust Zone, a major collisional zone in north-west Scotland. The most northerly of these is the Loch Loyal Syenite Complex, which comprises three separate intrusions. One of these, the Cnoc nan Cuilean intrusion, contains two mappable zones: a Mixed Syenite Zone in which mafic melasyenite is mixed and mingled with leucosyenite and a Massive Leucosyenite Zone. Within the Mixed Syenite Zone, hydrothermal activity is evident in the form of narrow altered veins dominated by biotite and magnetite; these are poorly exposed and their lateral extent is uncertain. The REE mineral allanite is relatively abundant in the melasyenite and is extremely enriched in the biotite-magnetite veins, which have up to 2 % total rare earth oxides in bulk rock analyses. An overall model for development of this intrusion can be divided into three episodes: (1) generation of a Light Rare Earth Element (LREE)-enriched parental magma due to enrichment of the mantle source by subduction of pelagic carbonates; (2) early crystallisation of allanite in melasyenite, due to the saturation of the magma in the LREE; and (3) hydrothermal alteration, in three different episodes identified by petrography and mineral chemistry, generating the intense enrichment of REE in the biotite-magnetite veins. Dating of allanite and titanite in the biotite-magnetite veins gives ages of c. 426 Ma, overlapping with previously published crystallisation ages for zircon in the syenite.

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Rubidium and strontium are used as tracers in the history of differentiation of the continental sial, and for this purpose it is assumed that the Rb/Sr ratio, follows the aggregate enrichment of sialic components sufficiently well to represent an approximately linear measure of the entire process. Measurements of the Sr•/Sr •6 ratios in basalts and other igneous rocks of subsialic origin suggest that the source regions of sial have had a SrS7/Sr• ratio in the range 0.705 to 0.710 in different areas and at different times in the span of geologic history. Measurements of the Rb/Sr ratio in sialic rocks of the continental crystalline basement have indicated that the weighted average value for this ratio is in the vicinity of 0.25. This means that the SrS*/Sr•6 ratio in average sialic rocks of the continental basement would increase at a faster rate than that in the subsialic source regions, by an amount equal to approximately 0.010 per billion years. This is more than five times the standard deviation precision error in measurement. A comparison of the ratio SrS7/Sr • with the geologic age of the rock, in samples of typical sialic basement rocks leads to the conclusion that there has been a continuous generation of primary sial from subsialic source regions that has caused the continental areas to grow roughly in proportion to the extent of the geological age provinces. In North America this areal growth is estimated to be at the average rate of about 7000 kmym.y., and it seems to have been operative over most of geologic time. A model is formulated in which the proportion and age of reworked material that is incorporated into new sialic basement are related to the SrS*/Sr• development in the various materials involved. The model is generalized with all the parameters left open. An example set of values for the various parameters is tested on the model to indicate where there is need for more definitive data. This example set is derived from data available at present which, although very limited, indicate clearly that if the reworked material is young enough it can constitute a major proportion of a new sialic basement area, but if it is ancient (1 to 2 b.y. in primary age prior to incorporation) it could not be present in more than a minor proportion of the typical new basement. The abundance of SF * is related to the abundance of its parent Rb 8' in the materiM and to the time since separation of the rocks from a source at depth. We believe that the pair of elements Rb-Sr is better suited for this study than the pair U-Pb because of the great geochemical dissimilarity of the former. As a result Rb and Sr are more efficienfiy separated from each other than U and Pb during the dif-1 M.I.T. Age Studies, No. 36.ferentiation of sialic crust from its source regions. It is granted that the long half-life of Rb •7 does not create the magnitude of change in the Sr • abundance that is produced in the radiogenic isotopes of lead and that measurements of variations are therefore less precise. Nevertheless, we are currently co...