Incorporation of pyridol into 12-membered pyridinophanes results in exceptional metabolic stability, low-toxicity, and controlled metal binding suggesting good pharmacological potential.
Pyclen and cylen complexes of manganese show pH dependent catalase activity with improved TOF and TON for the more rigid pyclen derivative. Spectroscopic investigation shows O2 evolution corresponds with the presence of a μ-O bridged species.
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