The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η5-C5H4)(η5-C5H5)] and one CH2Cl2 solvent molecule. The geometry around the RuII atom is pseudo-octahedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2]2− ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H⋯O hydrogen bonds link adjacent molecules into dimers.
In the cluster cation of the title compound, [Mo3S7-(Et2NCS2)3](Et2NCS2), three Mo atoms form an approximately equilateral triangle, with Mo---Mo distances ranging from 2.7140(5) to 2.7277 (5).4,, and Mo--Mo---Mo angles of ca 60 °. The triangle is capped by the/z3-S atom, and each Mo---Mo bond is bridged by a disulfido group in #2-772 mode. Diethyldithiocarbamate ligands (Et2dtc) are chelated to the Mo atoms with an average S--Mo--S bite angle of 69.98 (1) °. There is a weak S-.-S interaction between the cluster cation and the anion (Et2dtc-).
CommentCompounds containing the [MOBS7] ~ core have been studied extensively (Miiller et al., 1979;Keck et al.,
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