The origin of water on the Earth is a long-standing mystery, requiring a comprehensive search for hydrous compounds, stable at conditions of the deep Earth and made of Earthabundant elements. Previous studies usually focused on the current geothermal situation in the Earth's mantle and ignored a possible difference in the past, such as the stage of the core-mantle separation. Here, using ab initio evolutionary structure prediction, we find that only two magnesium hydrosilicate phases are stable at megabar pressures, α-Mg2SiO5H2 and β-Mg2SiO5H2, stable at 262-338 GPa and >338 GPa, respectively (all these pressures now lie within the Earth's iron core). Both are superionic conductors with quasi-one-dimensional proton diffusion at relevant conditions. In the first 50-100 million years of Earth's history, before the Earth's core was formed, these must have existed in the Earth, hosting much of Earth's water. As dense iron alloys segregated to form the Earth's core, Mg2SiO5H2 phases decomposed and released water. Thus, now-extinct Mg2SiO5H2 phases have likely contributed in a major way to the evolution of our planet.
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