A new nitrogen sulphur Schiff base has been prepared from the condensation 1-(pyridin-4-yl) ethanone with 3-methylbenzyl hydrazinecarbodithioate leading the formation of new ligand 3methylbenzyl (2Z)-2-[1-(pyridin-4-yl)ethylidene]hydrazine carbodithioate (PE3MBC). The ligand was reacted with Cd(II) and Zn(II) metal salts to form new coordinated complexes. The new ligand and its metal complexes were characterized via various physico-chemical and spectroscopic techniques and conductivity, magnetic susceptibility of metal complexes based on the data analysis the metal complexes are expected to be tetrahedral in geometry.
Novel bidentate Schiff bases having nitrogen-sulphur donor sequence was synthesized from condensation of racemate camphor, (R)-camphor and (S)-camphor with Methyl hydrazinecarbodithioate (SMDTC). Its metal complexes were also prepared through the reaction of these ligands with silver and bismuth salts. All complexes were characterized by elemental analyses and various physico-chemical techniques. These Schiff bases behaved as uninegatively charged bidentate ligands and coordinated to the metal ions via ?-nitrogen and thiolate sulphur atoms. The NS Schiff bases formed complexes of general formula, [M(NS)2] or [M(NS)2.H2O] where M is BiIII or AgI, the expected geometry is octahedral for Bi(III) complexes while Ag(I) is expected to oxidized to Ag(II) forming square planner complexes.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.