The aim of this project is to create a geochemical database of the Nafud Desert in Zilfi Province, which lies 260 km northwest of Riyadh, capital of Saudi Arabia, and assess its potential as a silicon mine. The area of study was surveyed during December 2012 collecting 21 geological samples from 7 places (Alsabla, Almatal, Shlwan, Alaaga, Jaway, Magra and Althuare).Elemental composition was determined using X-ray fluorescence spectrometry, while mineral content and crystallography analysis was performed using X-ray diffraction.Analysis results revealed that silicon was abundant in the area, in fairly homogeneous amounts. Silica was found in concentrations of around 93% per sampled mass, and silicon concentrations were around 42%, in the surface layers down to the depth of 40 cm.Other elements (Al, K, Ca, Ti, Cr, Mn, Fe, Sr, Zr and Pd ) were present in very low concentrations, except for aluminium oxide, which was present in three areas (Jaway, Magra and Althuare) at concentrations around 5%, while Alsabla samples showed higher concentrations of CaO. Thus, according to the results, the Nafud Desert is a rich source of silicon that can be exploited very cheaply because of the presence of the raw material on the surface.