The demonstrated square-planar Pt(II)-complex has reduced triplet-triplet quenching and therefore a near unity quantum yield in the neat thin film. A non-doped phosphorescent organic light-emitting diode (PhOLED) based on this emitter achieves (31.1 ± 0.1)% external quantum efficiency without any out-coupling, which shows that a non-doped PhOLED can be comparable in efficiency to the best doped devices with very complicated device structures.

An experimental and computational study of correlations between solid-state structure and optical/electronic properties of cyclotrimeric gold(I) carbeniates, [Au3(RN═COR')3] (R, R' = H, Me, (n)Bu, or (c)Pe), is reported. Synthesis and structural and photophysical characterization of novel complexes [Au3(MeN═CO(n)Bu)3], [Au3((n)BuN═COMe)3], [Au3((n)BuN═CO(n)Bu)3], and [Au3((c)PeN═COMe)3] are presented. Changes in R and R' lead to distinctive variations in solid-state stacking, luminescence spectra, and conductive properties. Solid-state emission and excitation spectra for each complex display a remarkable dependence on the solid-state packing of the cyclotrimers. The electronic structure of [Au3(RN═COR')3] was investigated via molecular and solid-state simulations. Calculations on [Au3(HN═COH)3] models indicate that the infinitely extended chain of eclipsed structures with equidistant Au--Au intertrimer aurophilic bonding can have lower band gaps, smaller Stokes shifts, and reduced reorganization energies (λ). The action of one cyclotrimer as a molecular nanowire is demonstrated via fabrication of an organic field effect transistor and shown to produce a p-type field effect. Hole transport for the same cyclotrimer-doped within a poly(9-vinylcarbazole) host-produced a colossal increase in current density from ∼1 to ∼1000 mA/cm(2). Computations and experiments thus delineate the complex relationships between solid-state morphologies, electronic structures, and optoelectronic properties of gold(I) carbeniates.

The information-rich vessel movement data provided by the Automatic Identification System (AIS) has gained much popularity over the past decade, during which the employment of satellite-based receivers has enabled wide coverage and improved data quality. The application of AIS data has developed from simply navigation-oriented research to now include trade flow estimation, emission accounting, and vessel performance monitoring. The AIS now provides high frequency, real-time positioning and sailing patterns for almost the whole world's commercial fleet, and therefore, in combination with supplementary databases and analyses, AIS data has arguably kickstarted the era of digitization in the shipping industry.In this study, we conduct a comprehensive review of the literature regarding AIS applications by dividing it into three development stages, namely, basic application, extended application, and advanced application. Each stage contains two to three application fields, and in total we identified seven application fields, including (1) AIS data mining, (2) navigation safety, (3) ship behavior analysis, (4) environmental evaluation, (5) trade analysis, (6) ship and port performance, and (7) Arctic shipping. We found that the original application of AIS data to navigation safety has, with the improvement of data accessibility, evolved into diverse applications in various directions. Moreover, we summarized the major methodologies in the literature into four categories, these being (1) data processing and mining, (2) index measurement, (3) causality analysis, and (4) operational research.Undoubtedly, the applications of AIS data will be further expanded in the foreseeable future. This will not only provide a more comprehensive understanding of voyage performance and allow researchers to examine shipping market dynamics from the micro level, but also the abundance of AIS data may also open up the rather opaque aspect of how shipping companies release information to external authorities, including the International Maritime Organization, port states, scientists and researchers. It is expected that more multi-disciplinary AIS studies will emerge in the coming years. We believe that this study will shed further light on the future development of AIS studies.

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Today's state‐of‐the‐art phosphorescent organic light‐emitting diodes (PhOLEDs) must rely on the host‐guest doping technique to decrease triplet quenching and increase device efficiency. However, doping is a sophisticated device fabrication process. Here, a Pt(II)‐based complex with a near unity photoluminescence quantum yield and excellent electron transporting properties in the form of neat film is reported. Simplified doping‐free white PhOLED and yellow‐orange PhOLED based on this emitter achieve rather low operating voltages (2.2–2.4 V) and very high power efficiencies of approximately 80 lm W−1 (yellow‐orange) and 50 lm W−1 (white), respectively, without any light extraction enhancement. Furthermore, the efficient white device also exhibits high color stability. No color shift is observed during the entire operation of the device. Analysis of the device's operational mechanism has been postulated in terms of exciton and polaron formation and fate. It is found that using the efficient neat Pt(II)‐complex as a homogeneous emitting and electron transporting layer and an ambipolar blue emitter are determining factors for achieving such a high efficiency.