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Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors, are suitable for applications in high-efficiency and cost-effective photovoltaics (PVs), and provide adaptability to the needs of architects for building-integrated PVs, which makes them an attractive option for transforming buildings into transparent or non-transparent electricity generators. Compared with traditional organic dyes, colloidal semiconducting quantum dots (QDs) are excellent candidates as emitters for LSCs because they exhibit wide size/shape/composition-tunable absorption spectra ranging from ultraviolet to near infrared, significantly overlapping with the solar spectrum. They also feature narrow emission spectra, high photoluminescence quantum yields, high absorption coefficients, solution processability and good photostability. Most importantly, QDs can be engineered to provide a minimal overlap between absorption and emission spectra, which is key to the realization of large-area LSCs with largely suppressed reabsorption energy losses. In this review article, we will first present and discuss the working principle of LSCs, the synthesis of colloidal QDs using wet-chemistry approaches, the optical properties of QDs, their band alignment and the intrinsic relationship between the band energy structure and optical properties of QDs. We focus on emerging architectures, such as core/shell QDs. We then highlight recent progress in QD-based LSCs and their anticipated applications. We conclude this review article with the major challenges and perspectives of LSCs in future commercial technologies.

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The fabrication of a low reabsorption emission loss, high efficient luminescent solar concentrator (LSC) is demonstrated by embedding near infrared (NIR) core/shell quantum dots (QDs) in a polymer matrix. An engineered Stokes shift in NIR core/shell PbS/CdS QDs is achieved via a cation exchange approach by varying the core size and shell thickness through the refined reaction parameters such as reaction time, temperature, precursor molar ratio, etc. The as‐synthesized core/shell QDs with high quantum yield (QY) and excellent chemical/photostability exhibit a large Stokes shift with respect to the bare PbS QDs due to the strong core‐to‐shell electrons leakage. The large‐area planar LSC based on core/shell QDs exhibits the highest value (6.1% with a geometric factor of 10) for optical efficiency compared to the bare NIR QD‐based LSCs and other reported NIR QD‐based LSCs. The suppression of emission loss and the broad absorption of PbS/CdS QDs offer a promising pathway to integrate LSCs and photovoltaic devices with good spectral matching, indicating that the proposed core/shell QDs are strong candidates for fabricating high efficiency semi‐transparent large‐area LSCs.