White hybrid light‐emitting diodes (WHLEDs) are considered as a solid approach toward environmentally sustainable lighting sources that meet the “Green Photonics” requirements. Here, WHLEDs with protein‐based down‐converting coatings, i.e., Bio‐WHLEDs, are demonstrated and exhibit worthy white color quality, luminous efficiency, and stability values. The coatings feature a multilayered cascade‐like architecture with thicknesses of 1–3 mm. This limits the efficiency due to the low optical transmittance. Thus, submillimeter coatings, where the location of the proteins is well‐defined, are highly desired. It is in this context where the thrust of this work sets in. Here, a straightforward way to design microstructured single‐layer coatings, in which the proteins are placed at our command by using 3D printing, is presented. Based on comprehensive spectroscopic and rheological investigations, the optimization of the matrix and the plotting to prepare different micropatterns, i.e., lines, open‐grids, and closed‐grids, is rationalized. The latter are applied to prepare Bio‐WHLEDs with ≈5‐fold enhancement of the luminous efficiency compared to the reference devices with a cascade‐like coating, without losing stability and color quality. As such, this work shows a new route to exploit proteins for optoelectronics, setting a new avenue of research into the emerging field of Bio‐WHLEDs.
Herein, we provide a new easy-to-do protocol for preparing luminescent rubber-like materials based on a wide palette of compounds, such as small-molecules, quantum dots, polymers, and coordination complexes. The combination of this new protocol with that for preparing similar rubbers based on fluorescent proteins states the universal character of our approach. This is further assessed by using comprehensive spectroscopic and rheological investigations.Furthermore, the novel luminescent rubbers are applied as downconverting packing systems to develop white hybrid light-emitting diodes (WHLEDs), which are heralded as a solid alternative to achieve energy-saving, solid-state, and white-emitting sources in the coming future. As such, the current work also provides a clear prospect of this emerging lighting technology by means of a direct comparison among WHLEDs fabricated with all the above-mentioned down-converting systems. Here, the use of rubbers based on coordination complexes outperforms the others in terms of both luminous efficiency and colour quality with an unprecedented stability superior to 1000 h under continuous operation conditions. This represents an order of magnitude enhancement compared to the state-of-the-art WHLEDs, while keeping luminous efficiencies of around 100 lm W À1 .
During the last decades, the rheology of cells has been studied almost entirely in single cells. While cell-to-cell variation is typically very large and most studies were carried out in the nonlinear viscoelastic regime, we quantify average linear viscoelastic cell properties like storage and loss moduli and normal stress in monolayers of different cell types showing that murine 3T6 fibroblasts, human fibroblasts, and HeLa cells differ considerably in their storage modulus. To this end, we modified a commercial rheometer to set up a parallel-disk configuration at gap widths of a few micrometers and optically detected the cell concentration in the gap. This enables studying the linear viscoelastic behavior of the cells and permits quantifying the impact of drugs affecting the cytoskeleton or the extracellular matrix connection. Thus, due to its high-content approach, without the need of treating the samples in the rheometer, this envisions the use of this method as a fast diagnostic tool. The method also allows for quantitatively studying of the impact of pre-stress on the storage and loss moduli of the cells
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