The tensile fatigue tests and S-N curve fitting results of the coupling bolt material 25CrMo were given in this paper. It has been proved that the high-cycle fatigue properties of the bolt material can be accurately described by the three-parameter exponential S-N curve model by comparing the fitting results based on different S-N curve models. The fatigue limit of the high-cycle P-S-N curve calculated by the traditional maximum likelihood method was proved to have a high probability of being higher than the accurate fatigue limit. Therefore, a modified method based on maximum likelihood method was proposed so as to calculate the high-cycle P-S-N curve more accurately. The P-S-N of 25CrMo calculated using the modified method was given in this paper.
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