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Summary: The polymerization of ε‐caprolactone (CL) in the presence of HCl · Et2O by an activated monomer mechanism was performed to synthesize diblock or triblock copolymers composed of poly(ethylene glycol) (PEG) and poly(ε‐caprolactone) (PCL). The obtained PCLs had molecular weights close to the theoretical values calculated from the CL to PEG molar ratios and exibited monomodal GPC curves. We successfully prepared PEG and PCL block copolymers by a metal‐free method.

Poly(ethylene glycol) and poly(trimethylene carbonate) block copolymers were prepared successfully at room temperature by the living ring‐opening polymerization of trimethylene carbonate with poly(ethylene glycol) as an initiator in the presence of HCl·Et2O as a monomer activator.

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